UID:
edocfu_9958128981902883
Format:
1 online resource (409 p.)
ISBN:
1-299-38604-0
Series Statement:
Asymmetric synthesis ; v. 5
Content:
The chapters in this volume have been written by some of the foremost practictioners in the field and should be of interest to both mechanistic and synthetic chemists.
Note:
Description based upon print version of record.
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Front Cover; Asymmetric Synthesis; Copyright Page; Dedication; Table of Contents; Contributors; Preface; Chapter 1. Chiral Ligands for Asymmetrie Catalysis; I. Introduction; II. Chiral Phosphines; III. Chiral Amines; IV. Chiral Alcohols; V. Chiral Amides and Hydroxamic Acids; VI. Chiral Dioximes; VII. Chiral Sulfoxides and Arsines; VIII. Chiral Cyclopentadienyl Complexes; IX. Chiral Crown Ethers; X. Chiral 1,3-Diketones; XI. Conclusions; References; Chapter 2. Asymmetrie Catalytic Hydrogenation: Mechanism and Origin of Enantioselection; I. Introduction
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II. Approaches to the Elucidation of MechanismIII. Chiral Phosphine Ligands; IV. Effect of Substrate Structure; V. Tracer Experiments Using D2 and HD; VI. Kinetic and Related Mechanistic Studies; VII. Origin of the Difference in Stability and Reactivity of the Diastereomeric Catalyst-Substrate Adducts; VIII. Relation of Enantioselectivity to Substrate-Catalyst Binding; IX. Concluding Remarks: Relevance to Other Stereoselective Catalysts; References; Chapter 3. The Applicability of Asymmetric Homogeneous Catalytic Hydrogenation; I. Introduction
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II. Olefin Requirements for Efficient Asymmetric HydrogenationIII. Ketone Requirements for Efficient Asymmetric Hydrogenation; IV. Catalysts and Ligands; V. Conclusions; Appendix; References; Chapter 4. Asymmetric Hydrosilylation and Hydrocarbonylation; I. Introduction to Asymmetric Hydrosilylation; II. Asymmetric Hydrosilylation of Prochiral Carbonyl Compounds; III. Asymmetric Synthesis of Chiral Organosilicon Compounds via Hydrosilylation; IV. Asymmetric Reduction of Imines via Hydrosilylation; V. Asymmetric Hydrosilylation of Olefins; VI. Introduction to Asymmetric Hydrocarbonylation
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VII. Asymmetric HydroformylationVIII. Asymmetric Hydroesterification; IX. Summary; References; Chapter 5. Asymmetric Coupling Reactions; I. Introduction; II. Reaction of Organometallic Reagents with Alkenyl or ArylHalides; III. Reaction of Organometallic Reagents with Allylic Compounds; Addenda; References; Chapter 6. Asymmetric Catalytic Isomerization of Functionalized Olefins; I. Introduction; II. Allylic Alcohols and Derivatives; III. Allylamines and Derivatives; References; Chapter 7. Synthetic Aspects and Applications of Asymmetric Epoxidation; I. Introduction
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II. Asymmetric Epoxidation: Catalysts, Ligands, Substrates, and Reaction ConditionsIII. Stereoselectivity; IV. Examples of Synthetic Utility; V. Conclusions; References; Chapter 8. On the Mechanism of Asymmetric Epoxidation with Titanium--Tartrate Catalysts; Prologue; I. Introduction; II. Epoxidation Mechanisms; III. Asymmetric Epoxidations; IV. Asymmetric Epoxidation Mediated by Titanium-Tartrate; Epilogue; References; Chapter 9. Enzymes as Chiral Catalysts; I. Introduction; II. Types of Enzyme-Catalyzed Reactions; III. Coenzymes; IV. General Considerations; V. Enzyme Specificity
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VI. Exploitation of Enantiomeric Specificity
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English
Additional Edition:
ISBN 0-08-092493-X
Additional Edition:
ISBN 0-12-507705-X
Language:
English
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