UID:
almahu_9949198493102882
Format:
XXVIII, 584 p.
,
online resource.
Edition:
1st ed. 1977.
ISBN:
9781461397922
Note:
of Part A -- 1. Chemical Bonding and Molecular Structure -- 1.1. Valence-Bond Approach to Chemical Bonding -- 1.2. Bond Energies, Lengths, and Dipoles -- 1.3. Molecular Orbital Theory -- 1.4. Huckel Molecular Orbital Theory -- General References -- Problems -- 2. Stereochemical Principles -- 2.1. Enantiomeric Relationships -- 2.2. Diastereomeric Relationships -- 2.3. Dynamic Stereochemistry -- 2.4. Prochiral Relationships -- General References -- Problems -- 3. Conformational and Other Steric Effects -- 3.1. Steric Strain and Molecular Mechanics -- 3.2. Conformations of Acyclic Molecules -- 3.3. Conformations of Cyclohexane Derivatives -- 3.4. Carbocyclic Rings Other Than Six-Membered -- 3.5. Heterocyclic Conformational Analysis -- 3.6. Molecular Orbital Methods Applied to Conformational Analysis -- 3.7. Conformational Effects on Reactivity -- 3.8. Other Steric Effects on Reactivity -- General References -- Problems -- 4. Study and Description of Organic Reaction Mechanisms -- 4.1. Thermodynamic Data -- 4.2. Kinetic Data -- 4.3. Substituent Effects and Linear Free-Energy Relationships -- 4.4. Isotope Effects -- 4.5. Characterization of Reaction Intermediates -- 4.6. Catalysis -- 4.7. Solvent Effects -- 4.8. Basic Mechanistic Concepts: Kinetic Versus Thermodynamic Control, Hammond's Postulate, the Curtin-Hammett Principle -- 4.9. Isotopes in Labeling Experiments -- 4.10. Stereochemistry -- General References -- Problems -- 5. Nucleophilic Substitution -- 5.1. The Limiting Cases-Substitution by the Ionization (Sn1) Mechanism -- 5.2. The Limiting Cases-Substitution by the Direct Displacement (SN2) Mechanism -- 5.3. Alternative Mechanistic Hypotheses -- 5.4. Carbonium Ions -- 5.5. Nucleophilicity -- 5.6. Leaving-Group Effects -- 5.7. Steric and Other Substituent Effects on Substitution and Ionization Rates -- 5.8. Stereochemistry of Nucleophilic Substitution -- 5.9. Secondary Kinetic Isotope Effects in Substitution Mechanisms -- 5.10. Neighboring-Group Participation -- 5.11. Carbonium Ion Rearrangements -- 5.12. Nonclassical Carbonium Ions and the Norbornyl Cation Problem -- 5.13. Synthetic Applications of Nucleophilic Substitution Reactions -- General References -- Problems -- 6. Polar Addition and Elimination Reactions -- 6.1. Addition of Hydrogen Halides to Alkenes -- 6.2. Acid-Catalyzed Hydration of Alkenes -- 6.3. Addition of Halogens -- 6.4. The E2, E1, and E1cb Mechanisms -- 6.5. Orientation Effects in Elimination Reactions -- 6.6. Stereochemistry of E2 Elimination Reactions -- 6.7. Dehydration of Alcohols -- 6.8. Eliminations Not Involving C-H Bonds -- General References -- Problems -- 7. Carbanions and Other Nucleophilic Carbon Species -- 7.1. Acidity of Hydrocarbons -- 7.2. Carbanions Stabilized by Functional Groups -- 7.3. Enols and Enamines -- General References -- Problems -- 8. Reactions of Carbonyl Compounds -- 8.1. Hydration and Addition of Alcohols to Aldehydes and Ketones -- 8.2. Addition-Elimination Reactions of Ketones and Aldehydes -- 8.3. Reactivity of Carbonyl Compounds toward Addition -- 8.4. Ester Hydrolysis and Related Reactions -- 8.5. Amide Hydrolysis -- 8.6. Acylation of Nucleophilic Oxygen and Nitrogen Groups -- 8.7. Intramolecular Catalysis -- General References -- Problems -- 9. Aromaticity and Electrophilic Aromatic Substitution -- 9.1. Aromaticity -- 9.2. Electrophilic Aromatic Substitution Reactions -- 9.3. Structure-Reactivity Relationships -- 9.4. Specific Substitution Mechanisms -- 9.5. Theoretical Treatments of Aromatic Substitution Reactions -- General References -- Problems -- 10. Concerted Reactions -- 10.1. Electrocyclic Reactions -- 10.2. Sigmatropic Rearrangements -- 10.3. Cycloaddition and Cycloelimination Reactions -- General References -- Problems -- 11. Photochemistry -- 11.1. General Principles -- 11.2. Orbital Symmetry Considerations Related to Photochemical Reactions -- 11.3. Photochemistry of Carbonyl Groups -- 11.4. Photochemistry of Alkenes and Dienes -- 11.5. Photochemistry of Aromatic Compounds -- General References -- Problems -- 12. Free-Radical Reactions -- 12.1. Generation and Characterization of Free Radicals -- 12.2. Characteristics of Reaction Mechanisms Involving Radical Intermediates -- 12.3. Free-Radical Substitution Reactions -- 12.4. Free-Radical Addition Reactions -- 12.5. Intramolecular Free-Radical Reactions -- 12.6. Rearrangement and Fragmentation Reactions of Free Radicals -- 12.7. Electron-Transfer Reactions -- General References -- Problems -- References for Problems.
In:
Springer Nature eBook
Additional Edition:
Printed edition: ISBN 9781461397946
Additional Edition:
Printed edition: ISBN 9780306250033
Additional Edition:
Printed edition: ISBN 9781461397939
Language:
English
DOI:
10.1007/978-1-4613-9792-2
URL:
https://doi.org/10.1007/978-1-4613-9792-2
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