UID:
almahu_9949983723102882
Format:
1 online resource (350 pages)
Edition:
1st ed.
ISBN:
9780443134296
,
0443134294
,
9780443134265
,
044313426X
Content:
Introduction to Solid State Chemistry by James E. House provides an extensive overview of the fundamental principles and reactions of solid state chemistry. The book covers a range of topics including ionic crystals, defects in solids, metal structures, diffusion, phase transitions, and kinetics of reactions in solids. It also explores practical techniques such as sintering, annealing, and chemical vapor deposition. The author's goal is to serve as a comprehensive teaching resource for students and educators, providing both theoretical insights and practical applications. House draws on his extensive experience in chemistry to present complex concepts in an accessible manner, making it suitable for advanced undergraduate and graduate students.
Note:
Intro -- Introduction to Solid State Chemistry -- Copyright -- Contents -- About the author -- Preface -- A note on units -- Chapter 1: Energy and space factors in ionic crystals -- 1.1. Bonds between atoms -- 1.2. Energy considerations and Madelung constants -- 1.3. Ionic sizes and crystal environments -- 1.4. The Kapustinskii equation -- 1.5. Crystal forms -- 1.6. Common crystal structures -- 1.7. Electrostatic bond character considerations -- 1.8. Other uses of thermochemistry cycles -- 1.9. Hardness -- References -- Chapter 2: Defects in solids -- 2.1. The Boltzmann distribution law -- 2.2. Schottky defects -- 2.3. Frenkel defects -- 2.4. F-center defects -- 2.5. Substituted ion defects (impurities) -- 2.6. Kröger-Vink notation -- 2.7. Consequences of defects -- 2.8. Extended defects -- References -- Chapter 3: Metals -- 3.1. Structures of metals as arrangements of spheres -- 3.2. Bonding in metals -- 3.3. Heat capacity of metals -- 3.4. Electrical and thermal conductivity -- 3.5. Alloys -- 3.6. Zintl phases -- References -- Chapter 4: Diffusion, sintering, and annealing -- 4.1. Energy factors in diffusion -- 4.2. Diffusion mechanisms -- 4.3. Sintering -- 4.4. Annealing -- References -- Chapter 5: Phase transitions and thermochromism -- 5.1. Methods of thermal analysis -- 5.2. Dilatometry -- 5.3. The nature of some phase transitions -- 5.4. Phase transitions in metals -- 5.5. Thermodynamics of phase transitions -- 5.6. Mechanisms of phase transitions -- 5.7. Thermochromism -- References -- Chapter 6: Kinetics and mechanisms of reactions in solids -- 6.1. Extent of reaction -- 6.2. Effects of particle size and sample treatment -- 6.3. Effect of temperature on rates -- 6.4. First-order reactions -- 6.5. Second-order reactions -- 6.6. The parabolic rate law -- 6.7. Contracting volume rate law -- 6.8. Rate laws based on nucleation.
,
6.9. Some illustrations based on Avrami rate laws -- 6.10. Autocatalysis -- 6.11. A summary of rate laws -- 6.12. Illustrations from the dehydration of copper sulfate pentahydrate -- 6.13. Nonisothermal kinetics -- References -- Chapter 7: Some techniques for transforming solids -- 7.1. Reactions of solids -- 7.2. Mechanochemistry and ball milling -- 7.3. Ultrasound -- 7.4. Carbothermic reduction -- 7.5. The Acheson process -- 7.6. The Verneuil (flame fusion) method -- 7.7. The Czochralski method -- 7.8. Chemical vapor deposition -- 7.9. Spray pyrolysis -- References -- Chapter 8: Reactions of solid coordination compounds -- 8.1. Some basic aspects of coordination chemistry -- 8.2. Crystal field effects in spinels -- 8.3. Ligand field effects in forming transition states -- 8.4. Linkage isomerization -- 8.5. Anation -- 8.6. Geometrical isomerization -- 8.7. Racemization -- 8.8. Some concluding remarks -- References -- Chapter 9: Solids and energy -- 9.1. Batteries -- 9.2. Piezoelectric effect -- 9.3. Seebeck and Peltier effects -- 9.4. Semiconductors -- 9.5. Light-emitting diodes -- 9.6. Utilization of solar energy -- 9.7. Photovoltaic compounds containing main group elements -- 9.8. Photovoltaic perovskite compounds -- 9.9. Splitting of water -- References -- Chapter 10: Some solids of significance -- 10.1. Calcium carbonate and lime -- 10.2. Concrete -- 10.3. Aluminum oxide and silicon carbide -- 10.4. Aluminum oxynitride (ALON) -- 10.5. Titanium dioxide -- 10.6. Carbon -- 10.7. Silica and silicates -- 10.8. Zeolites -- 10.9. Glass -- 10.10. Silver iodide -- References -- Index.
Language:
English
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