UID:
almafu_9958089888402883
Umfang:
1 online resource (271 p.)
ISBN:
1-281-77365-4
,
9786611773656
,
0-08-086806-1
Serie:
Their Comprehensive chemical kinetics ; 12
Inhalt:
Electrophilic Substitution at a Saturated Carbon Atom
Anmerkung:
Description based upon print version of record.
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Front Cover; Comprehensive Chemical Kinetics, Volume 12; Copyright Page; Contents; Preface; Chapter 1. Introduction; REFERENCES; Chapter 2. The formation and reactions of carbanions; 1. GENERAL THERMODYNAMIC CONSIDERATIONS; 2. FORMATION OF CARBANIONS FROM HYDROCARBONS; 3. REACTIONS AND PROPERTIES OF CARBANIONS; REFERENCES; Chapter 3. Mechanisms of electrophilic substitution at saturated carbon; 1. THE FUNDAMENTAL MECHANISMS; 2. SUBSTITUTION WITH REARRANGEMENT; 3. MECHANISMS INVOLVING NUCLEOPHILIC OR ANIONIC CATALYSIS; REFERENCES; Chapter 4. The unimolecular mechanism. SE1
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1. SUBSTITUTIONS IN ORGANOMERCURY COMPOUNDS2. SUBSTITUTIONS IN OTHER ORGANOMETALLIC COMPOUNDS; REFERENCES; Chapter 5. Mercury-for-mercury exchanges; 1. THE ONE-ALKYL MERCURY-FOR-MERCURY EXCHANGE; 2. THE TWO-ALKYL (Syn-PROPORTIONATION) MERCURY-FOR-MERCURY EXCHANGE; 3. THE TWO-ALKYL (SYMMETRISATION) MERCURY-FOR-MERCURY EXCHANGE; 4. THE THREE-ALKYL MERCURY-FOR-MERCURY EXCHANGE; REFERENCES; Chapter 6. Other metal-for-metal exchanges; 1. SUBSTITUTION OF ALKYL-METAL COMPOUNDS BY METAL SALTS; 2. ALKYL EXCHANGES BETWEEN COMPOUNDS RnM AND RmM'; REFERENCES
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Chapter 7. Acidolysis of organometallic compounds1. STEREOCHEMICAL STUDIES; 2. ACIDOLYSIS OF ORGANOMAGNESIUM CONPOUNDS; 3. ACIDOLYSIS OF DIALKYLZINCS AND OF DIALKYLCADMIUMS; 4. ACIDOLYSES OF ORGANOMERCURY COMPOUNDS; 5. ACIDOLYSIS OF TRIETHYLBORON BY CARBOXYLIC ACIDS; 6. ACIDOLYSIS OF THE ALKYLS OF METALS IN GROUP IVA; 7. ACIDOLYSIS OF THE ALKYLS OF METALS IN GROUP VIII AND GROUP V I B; REFERENCES; Chapter 8. Halogenolysis (halogenodemetallation) of organometallic compounds; 1. STEREOCHEMICAL STUDIES; 2. HALOGENOLYSIS OF ORGANOMERCURY COMPOUNDS; 3. HALOGENOLYSIS OF TETRAALKYLTINS
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4. HALOGENOLYSIS OF TETRAALKYLLEADS5. IODINE BROMIDE CLEAVAGE OF TETRAALKYLTINS; 6. SOLVENT EFFECTS ON THE IODINOLYSIS OF TETRAALKYTINS AND TETRAALKYLLEADS; REFERENCES; Chapter 9. Other electrophilic substitutions of organometallic compounds; 1. THE STEREOCHEMICAL COURSE OF CARBONATION OF ALKYLLITHIUM AND ALKYLMAGNESIUM COMPOUNDS; 2. ADDITION REACTIONS OF ORGANOMAGNESIUM COMPOUNDS; 3. THE REACTION BETWEEN DIALKYLZINCS AND BENZALDEHYDE; 4. ALKYLATION OF TRIARYLBROMOMETHANE BY ALKYLMERCURIC HALIDES; 5. CLEAVAGES OF ALKYLBORONIC ACIDS
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6. ADDITION OF TRIALKYLALUMINIUMS TO NITRILES, ESTERS, AND KETONES7. DISPROPORTIONATION OF T'ETRAALKYLSILANES CATALYSED BY ALUMINIUM BROMIDE; 8. THE OXIDATION OF TETRAALKYLTINS BY CHROMIUM TRIOXIDE IN SOLVENT ACETIC ACID; 9. THE DISPLACEMENT OF COBALT(III) AND CHROMIUM(III) FROM PYRIDIOMETHYLCOBALTATE IONS AND -CHROMIUM(III) IONS BY NITROSATING AGENTS; REFERENCES; Chapter 10. Electrophilic substitutions of allyl-metal compounds; 1. BASE CATALYSED SE1 CLEAVAGE OF 3-PHENALLYLSILICON AND -TIN COMPOUNDS; 2. METAL-FOR-METAL EXCHANGES OF ALLYL-METAL COMPOUNDS; 3. ACIDOLYSIS OF ALLYL-METAL COMPOUNDS
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4. HALOGENOLYSIS (HALOGENODEMETALLATION) OF ALLYL-METAL COMPOUNDS
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English
Weitere Ausg.:
ISBN 0-444-41052-X
Sprache:
Englisch
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