UID:
almafu_9958081203702883
Umfang:
1 online resource (579 p.)
ISBN:
1-281-77370-0
,
9786611773700
,
0-08-086808-8
Serie:
Their Comprehensive chemical kinetics ; v. 14
Inhalt:
Degradation of Polymers
Anmerkung:
Description based upon print version of record.
,
Front Cover; Comprehensive Chemical Kinetics, Volume 14; Copyright Page; Contents; Contributors to Volume 14; Preface; Chapter 1. Thermal degradation of polymers; 1. Introduction; 2. Experimental methods; 3. Kinetics of isothermal depolymerization; 4. Determination of kinetic parameters by temperature programmed methods; 5. Polyolefins and natural rubber; 6. Polystyrenes and polyvinylpyridine; 7. Polymethacrylates and polyacrylates; 8. Polyacrylonitrile and related polymers; 9. Polyvinylchloride; 10. Other vinyl polymers; 11. Polymers containing heteroatoms in the chain
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12. Fluorinated polymers13. Thermostable organic polymers; 14. Copolymers and polymer blends; References; Chapter 2. High energy degradation of polymers; 1. Introduction; 2. Characterization of intermediates in irradiated polymers; 3. Kinetic aspects of the formation and decay of intermediates; 4. Chemical effects of irradiation on solid polymers; 5. Mechanical properties of irradiated polymers; 6. Irradiation of polymer solutions; 7. General conclusions; References; Chapter 3. Photodegradation of polymers; 1. Introduction; 2. Experimental methods; 3. Photochemistry of hydrocarbon polymers
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4. Photochemistry of ketone polymers5. Photochemistry of methacrylate and acrylate polymers; 6. Photochemistry of polyvinyl esters; 7. Photochemistry of condensation polymers; 8. Stabilization of polymers against photodegradation; 9. Photophysics of polymers; References; Chapter 4. Oxidative degradation of polymers; 1. Introduction; 2. General mechanism of the oxidation of polymers; 3. The general mechanism of polymer photo-oxidation; 4. Other problems of the oxidation of polymers; 5. Physical aspects of oxidation of polymers; 6. The metal catalysed oxidation of high polymers
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7. Singlet oxygen mechanism of polymer oxidation8. Photosensitized oxidative degradation of polymers in solution; 9. Effect of atomic oxygen on polymers; 10. Effect of ozone on polymers; References; Index
,
English
Weitere Ausg.:
ISBN 0-444-41155-0
Sprache:
Englisch
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