UID:
almafu_9960073259502883
Format:
1 online resource (637 p.)
ISBN:
1-281-05840-8
,
9786611058401
,
0-08-053667-0
Series Statement:
Comprehensive Chemical Kinetics
Content:
This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decou
Note:
Description based upon print version of record.
,
Front Cover; Modern Aspects of Diffusion-Controlled Reactions: Cooperative Phenomena in Bimolecular Process; Copyright Page; Contents; Preface; Chapter 1. Guide to the book; 1.1 What is this book written for?; 1.2 Order and disorder; 1.3 How many particles are necessary to create a many-particle problem?; 1.4 Intermediate order; 1.5 Critical phenomena; References; Chapter 2. Basic methods for describing chemical kinetics in condensed media: continuum models; 2.1 Macroscopic approach; 2.2 The treatment of stochasticity on a mesoscopic level; 2.3 Microscopic treatment of stochasticity
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ReferencesChapter 3. From pair kinetics toward the many-reactant problem; 3.1 Basic defects and processes in solids; 3.2 Annealing of geminate pairs of defects; References; Chapter 4. The linear approximation in bimolecular reaction kinetics; 4.1 The shortened superposition approximation (A + B -» 0 reaction); 4.2 Tunnelling recombination; 4.3 Non-diffusion defect recombination and non-stationary kinetics; References; Chapter 5. The fluctuation-controlled kinetics: the basic formalism of many-point particle densities; 5.1 The A + B -〉 0 reaction; 5.2 The A + B -〉 B reaction
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5.3 The A + A -〉 0 and A + A -〉 A reactionsReferences; Chapter 6. The many-particle effects in irreversible A + B -〉 0 reaction; 6.1 Long-range recombination of immobile particles; 6.2 Kinetics of diffusion-controlled reactions of mobile non-interacting particles; 6.3 Dynamic particle aggregation induced by elastic interactions; 6.4 Effect of non-equilibrium charge screening (Coulomb interaction); References; Chapter 7. The many-particle effects in A + B -〉 0 reaction with particle generation; 7.1 The kinetics of defect accumulation under irradiation
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7.2 Diffusion-controlled particle aggregation under permanent source7.3 Other approaches; 7.4 Probabilistic models and computer simulations; References; Chapter 8. Systems under birth and death conditions: Lotka and Lotka-Volterra models; 8.1 A novel criterion of the marginal complexity insuring self-organization in the course of chemical reactions; 8.2 The Lotka-Volterra model; 8.3 The Lotka model; References; Chapter 9. Catalytic reactions on solid surfaces; 9.1 A stochastic model for surface reactions without energetic interactions
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9.2 A stochastic model for surface reactions including energetic particle interactionsReferences; Chapter 10. General conclusion; References; Author Index; Subject Index
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English
Additional Edition:
ISBN 0-444-82472-3
Language:
English
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