UID:
almahu_9948026172602882
Format:
1 online resource (577 p.)
ISBN:
1-281-98478-7
,
9786611984786
,
0-08-053885-1
Series Statement:
Comprehensive chemical kinetics ; v. 36
Content:
Many books cover the determination of rate constants under different experimental conditions and different chemical composition of the reaction mixture in their formal treatment of thermal kinetics. However, most textbooks are limited to simple mechanisms. In contrast, analogous treatment of photochemical reactions is limited to the publication of special reactions and investigations. Therefore, this book is aimed at providing an overall description of formal photokinetics covering a wider scope than the usual books on kinetics. This volume attempts to provide a concise treatment of both the
Note:
Description based upon print version of record.
,
Front Cover; Photokinetics Theoretical Fundamentals and Applications; Copyright Page; Contents; Preface; Chapter 1. Introduction; 1.1 General considerations; 1.2 Stoichiometry of chemical reactions; 1.3 Photophysics; 1.4 Photochemistry and photokinetics; Chapter 2. General approach in formal kinetics; 2.1 Fundamentals; 2.2 General approach to linear systems of reactions; 2.3 Information about reactions supplied by graphs; 2.4 Applications to selected systems; 2.5 Methods of approximation; Chapter 3. Special considerations for simple and complex photochemical reactions
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3.1 Relationship between quantum yield and mechanism3.2 Explicit differential equations in photokinetics; 3.3 The integration of the differential equation; 3.4 Photoreactions in viscous media; 3.5 Survey on approaches for selected examples; Chapter 4. Experimental techniques in photokinetic analysis; 4.1 Introduction; 4.2 Absorption measurement; 4.3 Fluorescence measurements; 4.4 Reflectance measurements; 4.5 Chromatographic methods; 4.6 Special methods; 4.7 Process control in kinetics; 4.8 Determination of intensity of irradiation
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Chapter 5. Applications of kinetic analysis to photoreactions5.1 Evaluation of measurements of concentrations; 5.2 Evaluation of measurements of concentrations; 5.3 Evaluation of linear dependent measured values; 5.4 Evaluation of absorbance-time measurements; 5.5 Fluorescence; 5.6 Combination of methods; 5.7 Photoreactions in viscous material; 5.8 Concluding remarks; 6. Appendix; 6.1 Reaction scheme; 6.2 Simple photochemical reactions; 6.3 Simple thermal reactions; 6.4 Examples for the determination of concentrations; 6.5 Consecutive reactions with superimposed back-reactions
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6.6 Relationship between quantum yield and photomechanism6.7 Example of a photokinetic evaluation; 7. References; Subject index
,
English
Additional Edition:
ISBN 0-444-82536-3
Language:
English
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