UID:
almafu_9959328607602883
Umfang:
1 online resource (xvi, 417 pages) :
,
illustrations
Ausgabe:
2nd ed.
ISBN:
9780470131442
,
0470131446
,
9780470131435
,
0470131438
,
9780471761297
,
047176129X
Inhalt:
An extensive update of the classic reference on organic reactions in water. Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories.
Anmerkung:
Introduction. The structure and forms of water ; Properties of water ; Solvation ; Hydrophobic effect ; Salt effect Water under extreme conditions -- Alkanes. Oxygenation of alkanes ; Halogenation of alkanes ; Formation of carbon-carbon bonds ; D/H exchange of alkanes in water --Alkenes. Reduction ; Electrophilic additions ; Radical reactions of alkenes ; Carbene reactions ; Alkene isomerization ; Transition-metal catalyzed C-C formation reactions ; Olefin metathesis ; Reaction of allylic C-H bond -- Alkynes. Reaction of terminal alkynes ; Additions of C [triple bar] C bonds ; Transition-metal catalyzed cycloadditions ; Other reactions.
,
Alcohols, Phenols, Ethers, Thiols, and Thioethers. Oxidation of alcohols ; Substitutions/elimination ; Addition of alcohols, phenols, and thiols to alkene and alkyne bonds ; Addition of alcohols to C=O bonds: esterification and acetal formations ; Reaction of ethers and cyclic ethers ; Other reactions -- Organic halides. General ; Reduction ; Elimination reactions ; Nucleophilic substitutions ; Reductive coupling ; Carbonylation of organic halides ; Transition-metal catalyzed coupling reactions -- Aromatic compounds. General ; Substitution reactions ; Oxidation reactions ; Reductions -- Aldehdye and ketones. Reduction ; Oxidation ; Nucleophilic addition: C-C bond formation ; Pinacol coupling ; Other reactions (Halogenation and oxidation of [alpha]-H).
,
Carboxylic acids and derivatives. General ; Carboxylic acids ; Carboxylic acid derivatives -- Conjugated carbonyl compounds. Reduction ; Epoxidation, dihydroxylation, hydroxyamination ; Conjugate addition: heteroatom ; C-C bond formation ; Other reactions -- Conjugated carbonyl compounds. Reduction ; Epoxidation, dihydroxylation, hydroxyamination ; Conjugate addition: heteroatom ; C-C bond formation ; Other reactions -- Nitrogen compounds. Amines ; Imines ; Diazo compounds ; Azides ; Nitro compounds -- Pericyclic reactions. Introduction ; Diels-Alder reactions ; Sigmatropic rearrangements ; Photochemical cycloaddition reactions.
Weitere Ausg.:
Print version: Li, Chao-Jun, 1963- Comprehensive organic reactions in aqueous media. Hoboken, N.J. : Wiley-Interscience, ©2007 ISBN 9780471761297
Weitere Ausg.:
ISBN 047176129X
Sprache:
Englisch
Fachgebiete:
Chemie/Pharmazie
Schlagwort(e):
Electronic books.
;
Electronic books.
;
Electronic books.
DOI:
10.1002/9780470131442
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9780470131442
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9780470131442
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9780470131442
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