UID:
almafu_9959327204802883
Umfang:
1 online resource (xii, 223 pages) :
,
illustrations
ISBN:
9780470139233
,
0470139234
,
9780470139226
,
0470139226
Inhalt:
The book is a technical guide for chemists and spectroscopists, and presents a concise description of magnetic circular dichroism (MCD) spectroscopy and how it has advanced the interpretation of molecular electronic spectra.Provides a practical guide to utilizing MCD spectroscopy for chemists starting in the fieldWritten by an expert with over twenty years of experience in the fieldHelps the reader to visualize the optical spectroscopic effects presented by MCD measurementsIncludes practical considerations for experimental MCD measurements based on the author's experience〈l.
Anmerkung:
A PRACTICAL GUIDE TO MAGNETIC CIRCULAR DICHROISM SPECTROSCOPY; CONTENTS; PREFACE; 1. Introduction; 2. Polarized Light; 2.1. Linear Polarization and Plane Polarized Waves; 2.2. Circular Polarization and Circularly Polarized Waves; 2.3. Absorption Probabilities; 3. Theoretical Framework: Definition of MCD Terms; 3.1. Born-Oppenheimer/Franck-Condon Approximation; 3.2. Rigid-Shift Approximation; 3.3. A(1)-, B(0)-, and C(0)-Term Parameters; 3.4. A Terms; 3.5. C Terms; 3.6. B Terms; 3.7. Pseudo A Terms: Overlapping B Terms; 3.8. Overlapping C Terms; 3.9. Ground-State Near Degeneracy
,
5.3. The Wigner-Eckart Theorem and Reduced Matrix Elements (RMEs)5.4. MCD-Term Equations Involving RMEs; 5.5. Evaluation of RMEs for MCD Terms; 5.6. Evaluation of Matrix Elements for LCAO-MO Functions; 5.7. Spin-Orbit Coupling Considerations; 5.8. Herzberg-Teller Approximation for Vibronic Transitions; 6. Case Studies I. Diamagnetic Systems: A and B Terms; 6.1. A and B Terms for Diamagnetic Atoms and Molecules; 6.2. Atomic Mercury Vapor; 6.3. The Sodide Ion Na(-) in a Solid NH(3) Matrix; 6.4. Square Complexes of D(4h) Symmetry; 6.4.1. Ligand Field Spectra for PtCl4(2-)(4)
Weitere Ausg.:
Print version: Mason, W. Roy. Practical guide to magnetic circular dichroism spectroscopy. Hoboken, N.J. : Wiley-Interscience, ©2007 ISBN 9780470069783
Weitere Ausg.:
ISBN 0470069783
Sprache:
Englisch
Schlagwort(e):
Electronic books.
;
Electronic books.
;
Electronic books.
DOI:
10.1002/9780470139233
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9780470139233
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9780470139233
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9780470139233
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