UID:
almahu_9949386474502882
Format:
1 online resource
Edition:
1st edition.
ISBN:
9781000062014
,
1000062015
,
9781003024385
,
1003024386
,
9781000061987
,
1000061981
,
9781000061956
,
1000061957
Series Statement:
Advances in Chromatography Ser. ; v. 57
Content:
For more than five decades, scientists and researchers have relied on the Advances in Chromatography series for the most up-to date information on a wide range of developments in chromatographic methods and applications. The clear presentation of topics and vivid illustrations for which this series has become known makes the material accessible and engaging to analytical, biochemical, organic, polymer, and pharmaceutical chemists at all levels of technical skill. This volume considers the achievements and legacy of Lloyd R. Snider in separation science and analytical chemistry. Key Features: Provides a historical perspective of the evolution of SMB technology together with a theoretical analysis of the most relevant underlying phenomena Presents a brief survey of the polar columns suitable for HILIC separations and pays special attention to the role of the mobile phase in RP and HILIC modes Describes recent strategies of method development in Kosmotropic chromatography Surveys the many approaches to avert the effects of temperature in reversed-phase liquid chromatographic separations Reviews separation of isotopic compounds by HPLC in relation to the advances of columns and stationary phases
Note:
Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- In Memoriam -- Editors -- List of Contributors -- Chapter 1 Mobile Phase Effects in Reversed-Phase and Hydrophilic Interaction Liquid Chromatography -- 1.1 Introduction -- 1.2 Stationary Phases in Liquid Chromatography -- 1.2.1 Sample Distribution in Liquid Chromatography -- 1.2.2 Stationary and Mobile Phase Volumes in Column Liquid Chromatography -- 1.2.2.1 Fully Porous Packing Particles -- 1.2.2.2 Core-Shell Columns -- 1.2.2.3 Monolithic Columns -- 1.2.2.4 Micro-Pillar Array Columns
,
1.3 Phase Systems and Separation Modes in HPLC -- 1.3.1 Organic Solvent Normal-Phase (Adsorption) Chromatography -- 1.3.2 Reversed-Phase Chromatography -- 1.3.3 Hydrophilic Interaction Liquid Chromatography (HILIC) -- 1.4 Mobile Phase Effects on Retention -- 1.4.1 Solvent Adsorption in the Stationary Phase -- 1.4.2 The Mobile Phase-Retention Models -- 1.4.3 Modeling Gradient-Elution Liquid Chromatography -- 1.4.4 Structural Retention Correlations -- 1.4.5 Combined-Retention-Mechanism LC Systems -- 1.4.5.1 Mixed-Mode and Zwitterionic Stationary Phases -- 1.4.5.2 Serially Coupled HILIC/RP Columns
,
1.4.5.3 Dual-Mode Retention Mechanism on a Single Column -- 1.5 Conclusions, Further Perspectives -- References -- Chapter 2 Temperature Effects in Reversed-Phase Liquid Chromatography: Use in Focusing, Temperature-Stable Stationary Phases, Effect on Retention, and Viscous Dissipation -- 2.1 Introduction -- 2.2 On-Column Solute Focusing -- 2.2.1 Overview -- 2.2.2 Solute Band Focusing Theory -- 2.2.3 Capillary-Scale TASF -- 2.2.3.1 Overview -- 2.2.3.2 Multiplicative TASF -- 2.2.4 Analytical Scale TASF -- 2.2.4.1 The Effect of Column Diameter -- 2.2.4.2 Precolumn Design
,
2.2.4.3 Experimental Results -- 2.3 Stable Stationary Phases -- 2.3.1 Overview -- 2.3.2 Silica Supports -- 2.3.2.1 Sterically Protected Stationary Phases -- 2.3.2.2 Polymer Modified Silica -- 2.3.2.3 Robust Silica Particles -- 2.3.3 Other Stationary Phase Supports -- 2.3.4 Stationary Phases Based on the Thiol-yne Reaction -- 2.4 The Influence of Temperature on Retention -- 2.4.1 Neutral Analytes -- 2.4.1.1 Background on Retention Models for Neutral Analytes -- 2.4.1.2 Comparing Retention Models for Neutral Analytes -- 2.4.2 Ionizable Analytes -- 2.4.2.1 Overview
,
2.4.2.2 Effect of Buffer Ionization Enthalpy -- 2.4.2.3 What Is the pH of a Mobile Phase? -- 2.4.2.4 Retention Prediction -- 2.4.2.5 Conclusion -- 2.4.3 Temperature-Dependent Changes in Stationary Phases -- 2.5 The Effects of Viscous Dissipation -- 2.5.1 Overview -- 2.5.2 Temperature Profiles within a Column -- 2.5.3 Counteracting Band Broadening Caused by Viscous Dissipation -- 2.5.4 Adiabatic Columns -- Acknowledgments -- References -- Chapter 3 Kosmotropic Chromatography of Proteins: Theory and Practice -- 3.1 Introduction -- 3.2 Kosmotropicity in Chromatography
Additional Edition:
Print version: ISBN 0367456125
Additional Edition:
ISBN 9780367456122
Language:
English
Keywords:
Electronic books.
;
Electronic books.
URL:
https://www.taylorfrancis.com/books/9781003024385
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