UID:
almahu_9949386948202882
Format:
1 online resource (1 volume) :
,
illustrations (black and white)
ISBN:
9781003183426
,
1003183425
,
1000404137
,
9781000404142
,
1000404145
,
9781000404135
Content:
This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T & F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.
Note:
11.8 Trace Elements Absorption -- 11.8.1 Inhibitors in Absorption -- 11.8.2 Enhancing the Effect of Absorption of Metals (even trace elements) -- 11.8.3 Toxic Metal Ion -- 11.8.4 Enzymes Inhibition -- 11.8.5 Detoxification by Metal Ion and Chelation -- 11.9 Metal Complexes in the Cure of Cancer -- 12. Uses and Applications of Coordination Complexes -- 12.1 Introduction -- 12.2 Applications of Metal Complexes -- 12.2.1 Dye Industry -- 12.2.2 Biological Enzymes -- 12.3 Polymer-Metal Complexes as Catalysts -- 12.3.1 Catalytic Activities of Polymers-Metal Complex -- 12.4 Application of Polymer-Metal Complexes as Catalysts -- 12.4.1 Oxidation -- 12.4.2 Hydrogenation -- 12.4.3 Hydrolysis -- 12.4.4 Hydroformylation of Olefins -- 12.5 Initiation of Radical Polymerisation -- 12.6 Asymmetric Synthetic and Optical Resolution -- 12.7 The decomposition of H2O2 -- 12.8 Polymer-metal complexes as Heterogeneous Biologically Active Catalysts -- 12.8.1 Porosity and Surface Area -- 12.8.2 Extent of Cross-Linking -- 12.8.3 Spacer Groups -- 12.8.4 Coordination Complex in Analytical Chemistry -- 12.8.5 Detecting Cations -- 12.8.6 Group I Cations -- 12.8.7 Confirmatory Test for Pb2+ Ions -- 12.8.8 Confirmatory Test for Ag+ Ions -- 12.8.9 Confirmatory Test for Mercury (1) ion -- 12.8.10 Group II Cations -- 12.8.11 Group reagent -- 12.9 Role of HCl in Group II Analysis -- 12.9.1 Group III Cations -- 12.9.2 Confirmatory Test for Fe3+, Al3+, Cr3+ -- 12.9.3 Group IV cations -- 12.9.4 Group Reagent -- 12.9.5 Confirmatory Tests -- 12.9.6 Group V cations -- 12.9.7 Group VI Cations -- 12.9.8 Zero Group Cations -- 12.9.9 Confirmatory Test for NH4+ ion -- 12.10 Detecting Anions -- 12.10.1 Group I Anions -- 12.10.2 Group of II Anions -- 12.11 Confirmatory Test for Cl- Ion -- 12.11.1 Chromyl Chloride Test -- 12.11.2 Br- and I- -- 12.11.3 Test for NO3- Ion -- 12.11.4 Test for C2O42- Ion.
,
12.11.5 Group III Anions -- 12.11.6 SO42- Ion Test -- 12.11.7 PO43- Ion Test -- 12.11.8 BO33- Ion Test -- 12.12 Modern Techniques -- 12.12.1 Quantitative Analysis -- 12.12.2 Quantitative Vs. Qualitative -- 12.13 Extraction of Metal from Complex Ores -- 12.14 High Temperature Chemical Reduction -- 12.14.1 Photography -- 12.14.2 Artificial Silk -- 12.15 Metal Complexes in Medicine -- 12.15.1 Platinum Anticancer Agents -- 12.15.2 Hydrolysis -- 12.15.3 Attack on DNA -- 12.15.4 Monofunctional Adducts -- 12.15.5 DNA Base Recognition by Pt Complexes -- 12.15.6 Binding to Meta Thiamine -- 12.15.7 Metallo Thionein and Glutathione -- 12.15.8 Targeting Via Transferring Receptor: Ruthenium and Titanium -- 12.16 Gold Antipathetic Drugs -- 12.17 Bismuth Anticancer Drugs -- 12.18 Conclusion -- 12.18.1 Metal Complexes as Drugs and Chemotherapeutic Agents -- 13. Metal Carbonyls and Nitosyls -- 13.1 Introduction -- 13.2 Preparation of Metal Carbonyls -- 13.3 Structure and Bonding in Carbonyls -- Coordinate Mononuclear Metal Carbonyls -- Applying EAN Rule to [Ni(CO)4] Complex -- 13.4 Iron Pentacarbonyl [Fe(CO)5] -- Physical Characteristics -- Structure and Bonding in [M(CO)5] -- Physical Characteristics -- 13.5 Polynuclear Metal Carbonyls -- Dimanganese decacarbonyl [Mn2(CO)10] -- Diironnonacarbonyl [Fe2(CO)9] -- 13.6 Dicobalt Octacarbonyl [Co2(CO)8] -- Tetranuclear Metal Carbonyls [M4(CO)12] -- 14. Organometallics -- 14.1 Introduction -- 14.2 Definition -- 14.3 Classification -- 14.4 Nomenclature -- 14.5 Synthesis Of Organometallic Compounds -- Synthesis of Sandwich Compounds -- Synthesis of Alkene Complexes -- Preparation of Zeise's Salt -- Synthesis of Alkyne Complexes -- Allyl Complexes -- Metal-Benzenoid Complexes -- Carbenes and Alkylidene Complexes -- Carbene and Alkalidyne Complexes -- Carbene Compounds -- Physical Characteristics -- Chemical Characteristics.
Additional Edition:
Print version: Soni, P.L. Chemistry of coordination complexes and transition metals. Boca Raton : CRC Press, 2021 ISBN 9781032024615
Language:
English
Keywords:
Electronic books.
DOI:
10.1201/9781003183426
URL:
https://www.taylorfrancis.com/books/9781003183426
Bookmarklink