UID:
almafu_9959327205002883
Umfang:
1 online resource (xiv, 433 pages) :
,
illustrations
ISBN:
9783527611003
,
3527611002
,
9783527611010
,
3527611010
Inhalt:
This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect:Numerous catalytic reductions and oxidations methodsSolid-acid and solid-base catalysisC-C bond formation reactionsBiocatalysisAsymmetric catalysisNovel reaction media like e.g. ionic liquids, supercritical CO2Renewable raw materialsWritten by Roger A. Sheldon--without doubt one of the leaders in the field with much experience in academia and industry--and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.
Anmerkung:
Cover -- Contents -- Preface -- Foreword -- 1 Introduction: Green Chemistry and Catalysis -- 1.1 Introduction -- 1.2. E Factors and Atom Efficiency -- 1.3 The Role of Catalysis -- 1.4 The Development of Organic Synthesis -- 1.5 Catalysis by Solid Acids and Bases -- 1.6 Catalytic Reduction -- 1.7 Catalytic Oxidation -- 1.8 Catalytic C-C Bond Formation -- 1.9 The Question of Solvents: Alternative Reaction Media -- 1.10 Biocatalysis -- 1.11 Renewable Raw Materials and White Biotechnology -- 1.12 Enantioselective Catalysis -- 1.13 Risky Reagents -- 1.14 Process Integration and Catalytic Cascades -- References -- 2 Solid Acids and Bases as Catalysts -- 2.1 Introduction -- 2.2 Solid Acid Catalysis -- 2.2.1 Acidic Clays -- 2.2.2 Zeolites and Zeotypes: Synthesis and Structure -- 2.2.3 Zeolite-catalyzed Reactions in Organic Synthesis -- 2.2.4 Solid Acids Containing Surface SO(3)H Functionality -- 2.2.5 Heteropoly Acids -- 2.3 Solid Base Catalysis -- 2.3.1 Anionic Clays: Hydrotalcites -- 2.3.2 Basic Zeolites -- 2.3.3 Organic Bases Attached to Mesoporous Silicas -- 2.4 Other Approaches -- References -- 3 Catalytic Reductions -- 3.1 Introduction -- 3.2 Heterogeneous Reduction Catalysts -- 3.2.1 General Properties -- 3.2.2 Transfer Hydrogenation Using Heterogeneous Catalysts -- 3.2.3 Chiral Heterogeneous Reduction Catalysts -- 3.3 Homogeneous Reduction Catalysts -- 3.3.1 Wilkinson Catalyst -- 3.3.2 Chiral Homogeneous Hydrogenation Catalysts and Reduction of the C= C Double Bond -- 3.3.3 Chiral Homogeneous Catalysts and Ketone Hydrogenation -- 3.3.4 Imine Hydrogenation -- 3.3.5 Transfer Hydrogenation using Homogeneous Catalysts -- 3.4 Biocatalytic Reductions -- 3.4.1 Introduction -- 3.4.2 Enzyme Technology in Biocatalytic Reduction -- 3.4.3 Whole Cell Technology for Biocatalytic Reduction -- 3.5 Conclusions -- References -- 4 Catalytic Oxidations -- 4.1 Introduction -- 4.2 Mechanisms of Metal-catalyzed Oxidations: General Considerations -- 4.2.1 Homolytic Mechanisms -- 4.2.2 Heterolytic Mechanisms -- 4.2.3 Ligand Design in Oxidation Catalysis -- 4.2.4 Enzyme Catalyzed Oxidations -- 4.3 Alkenes -- 4.3.1 Epoxidation -- 4.3.2 Vicinal Dihydroxylation -- 4.3.3 Oxidative Cleavage of Olefins -- 4.3.4 Oxidative Ketonization -- 4.3.5 Allylic Oxidations -- 4.4 Alkanes and Alkylaromatics -- 4.4.1 Oxidation of Alkanes -- 4.4.2 Oxidation of Aromatic Side Chains -- 4.4.3 Aromatic Ring Oxidation -- 4.5 Oxygen-containing Compounds -- 4.5.1 Oxidation of Alcohols -- 4.5.2 Oxidative Cleavage of 1,2-Diols -- 4.5.3 Carbohydrate Oxidation -- 4.5.4 Oxidation of Aldehydes and Ketones -- 4.5.5 Oxidation of Phenols -- 4.5.6 Oxidation of Ethers -- 4.6 Heteroatom Oxidation -- 4.6.1 Oxidation of Amines -- 4.6.2 Sulfoxidation -- 4.7 Asymmetric Oxidation -- 4.7.1 Asymmetric Epoxidation of Olefins -- 4.7.2 Asymmetric Dihydroxylation of Olefins -- 4.7.3 As.
Weitere Ausg.:
Print version: Sheldon, Roger A. Green chemistry and catalysis. Weinheim : Wiley-VCH ; Chichester : John Wiley [distributor], 2007 ISBN 9783527307159
Weitere Ausg.:
ISBN 352730715X
Sprache:
Englisch
Schlagwort(e):
Electronic books.
;
Electronic books.
;
Electronic books.
DOI:
10.1002/9783527611003
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527611003
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527611003
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527611003
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