UID:
almafu_9959327392702883
Format:
1 online resource (429 pages)
ISBN:
9783527690121
,
3527690123
,
9783527690145
,
352769014X
,
9783527690152
,
3527690158
,
3527337814
,
9783527337811
Content:
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Note:
Title Page; Copyright; Table of Contents; Preface; List of Contributors; Part I: Radical Chain Aerobic Oxidation; Chapter 1: Overview of Radical Chain Oxidation Chemistry; 1.1 Introduction; 1.2 Chain Initiation; 1.3 Chain Propagation; 1.4 Formation of Ring-Opened By-Products in the Case of Cyclohexane Oxidation; 1.5 Complications in the Case of Olefin Autoxidation; 1.6 Summary and Conclusions; References; Chapter 2: Noncatalyzed Radical Chain Oxidation: Cumene Hydroperoxide; 2.1 Introduction; 2.2 Chemistry and Catalysis; 2.3 Process Technology; 2.4 New Developments; References.
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Chapter 3: Cyclohexane Oxidation: History of Transition from Catalyzed to Noncatalyzed3.1 Introduction; 3.2 Chemistry and Catalysis; 3.3 Process Technology; 3.4 New Developments; Epilogue; References; Chapter 4: Chemistry and Mechanism of Oxidation of para-Xylene to Terephthalic Acid Using Co-Mn-Br Catalyst; 4.1 Introduction; 4.2 Chemistry and Catalysis; 4.3 Process Technology; 4.4 New Developments; 4.5 Conclusions; References; Part II: Cu-Catalyzed Aerobic Oxidation; Chapter 5: Cu-Catalyzed Aerobic Oxidation: Overview and New Developments; 5.1 Introduction; 5.2 Chemistry and Catalysis.
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5.3 Process Technology5.4 New Developments: Pharmaceutical Applications of Cu-Catalyzed Aerobic Oxidation Reactions; References; Chapter 6: Copper-Catalyzed Aerobic Alcohol Oxidation; 6.1 Introduction; 6.2 Chemistry and Catalysis; 6.3 Prospects for Scale-Up; 6.4 Conclusions; References; Chapter 7: Phenol Oxidations; 7.1 Polyphenylene Oxides by Oxidative Polymerization of Phenols; 7.2 2,3,5-Trimethylhydroquinone as a Vitamin E Intermediate via Oxidation of Methyl-Substituted Phenols; References; Part III: Pd-Catalyzed Aerobic Oxidation.
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Chapter 8: Pd-Catalyzed Aerobic Oxidation Reactions: Industrial Applications and New Developments8.1 Introduction; 8.2 Chemistry and Catalysis: Industrial Applications; 8.3 Chemistry and Catalysis: Applications of Potential Industrial Interest; 8.4 Chemistry and Catalysis: New Developments and Opportunities; 8.5 Conclusion; References; Chapter 9: Acetaldehyde from Ethylene and Related Wacker-Type Reactions; 9.1 Introduction; 9.2 Chemistry and Catalysis; 9.3 Process Technology (Wacker Process); 9.4 Other Developments; References; Further Reading; Chapter 10: 1,4-Butanediol from 1,3-Butadiene.
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10.1 Introduction10.2 Chemistry and Catalysis; 10.3 Process Technology; 10.4 New Developments; 10.5 Summary and Conclusions; References; Chapter 11: Mitsubishi Chemicals Liquid Phase Palladium-Catalyzed Oxidation Technology: Oxidation of Cyclohexene, Acrolein, and Methyl Acrylate to Useful Industrial Chemicals; 11.1 Introduction; 11.2 Chemistry and Catalysis; 11.3 Prospects for Scale-Up; 11.4 Conclusion; References; Chapter 12: Oxidative Carbonylation: Diphenyl Carbonate; 12.1 Introduction; 12.2 Chemistry and Catalysis; 12.3 Prospects for Scale-Up; 12.4 Conclusions and Outlook.
Additional Edition:
Print version: Stahl, Shannon S. Liquid Phase Aerobic Oxidation Catalysis : Industrial Applications and Academic Perspectives. Hoboken : Wiley, ©2016 ISBN 9783527337811
Language:
English
Keywords:
Electronic books.
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Electronic books.
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527690121
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527690121
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