UID:
almafu_9959242650802883
Format:
1 online resource (395 p.)
Edition:
1st ed.
ISBN:
9786611981785
,
9780080539577
,
0080539572
,
9780080514772
,
0080514774
,
9781281981783
,
1281981788
Series Statement:
Tetrahedron organic chemistry series ; v. 14
Content:
Principles of Asymmetric Synthesis
Note:
Description based upon print version of record.
,
Front Cover; Principles of Asymmetric Synthesis, Volume 14; Copyright Page; Table of Contents; Foreword; Asymmetric Synthesis-a Foreword; Preface; Reprint Acknowledgements; Chapter 1. Introduction; 1.1 Why we do asymmetric synthesis; 1.2 What is an asymmetric synthesis?; 1.3 Stereoselectivity: intraligand vs. interligand asymmetric induction; 1.4 Selectivity: kinetic and thermodynamic control; 1.5 Single and double asymmetric induction; 1.6 Glossary of stereochemical terms; 1.7 References; Chapter 2. Analytical Methods; 2.1 The importance of analysis, and which method to choose
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2.2 Polarimetry, the old fashioned way2.3 Nuclear magnetic resonance; 2.4 Chromatography; 2.5 Summary; 2.6 References; Chapter 3. Enolate, Azaenolate, and Organolithium Alkylations; 3.1 Enolates and azaenolates; 3.2 Chiral organolithiums; 3.3 References; Chapter 4. 1,2 and 1,4 Additions to Carbonyls; 4.1 Cram's rule: open-chain model; 4.2 Cram's rule: rigid, chelate, or cyclic model; 4.3 Additions using chiral catalysts or chiral nucleophiles; 4.4 Conjugate additions; 4.5 References; Chapter 5. Aldol and Michael Additions of Allyls and Enolates
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5.1 1,2-Additions of allyl metals and metalloids5.2 Aldol additions; 5.3 Michael additions; 5.4 References; Chapter 6. Rearrangements and Cycloadditions; 6.1 Rearrangements; 6.2 Cycloadditions; 6.3 References; Chapter 7. Reductions and Hydroborations; 7.1 Reduction of carbon-heteroatom double bonds; 7.2 Reduction of carbon-carbon bonds; 7.3 Hydroborations; 7.4 References; Chapter 8. Oxidations; 8.1 Introduction and Scope; 8.2 Epoxidations and related reactions; 8.3 Dihydroxylations; 8.4 Oxidation of enolates and enol ethers; 8.5 Miscellaneous Oxidations; 8.6 References; Index
,
English
Additional Edition:
ISBN 9780080418766
Additional Edition:
ISBN 0080418767
Additional Edition:
ISBN 9780080418759
Additional Edition:
ISBN 0080418759
Language:
English
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