UID:
almahu_9949983930202882
Umfang:
1 online resource (x, 330 pages) :
,
illustrations (some color).
ISBN:
9781283941501
,
1283941503
,
9780124046405
,
0124046401
Serie:
Advances in inorganic chemistry ; 65
Inhalt:
The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. * Features comprehensive reviews on the latest developments * Includes contributions from leading experts in the field * Serves as an indispensable reference t
Anmerkung:
"ISSN: 0898-8838."
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Front Cover; Homogeneous Catalysis; Copyright; Contents; Contributors; Preface; Chapter One: Homogeneous Multicopper Catalysts for Oxidation and Hydrocarboxylation of Alkanes; 1. Introduction; 2. Multicopper Complexes and Coordination Polymers; 3. Oxidation of Alkanes; 4. Hydrocarboxylation of Alkanes; 5. Final Comments; Acknowledgments; References; Chapter Two: Homogeneous Catalytic Olefin Epoxidation with Molybdenum Complexes; 1. Introduction; 2. Organomolybdenum Complexes Bearing a Mo-C σ-Bond; 3. η5-Cyclopentadienyl Molybdenum Complexes
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3.1. η5-Cyclopentadienyl molybdenum complexes bearing a halide or alkyl ligand3.2. Chiral organomolybdenum complexes; 3.3. Ansa-bridged η5-cyclopentadienyl molybdenum complexes; 3.4. Dinuclear η5-cyclopentadienyl molybdenum complexes; 3.5. η5-Cyclopentadienyl molybdenum complexes with NHC spectator ligands; 3.6. η5-Cyclopentadienyl molybdenum complexes with a π-allyl ligand; 4. Summary and Outlook; References; Chapter Three: Manganese and Iron Bleaching and Oxidation Catalysts; 1. Introduction; 2. Epoxidation of Alkenes; 2.1. General
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2.2. Manganese complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane ligands3. Cellulosic Bleaching; 3.1. Detergent applications; 3.1.1. General; 3.1.2. Activation of hydrogen peroxide by transition-metal complexes; 3.1.3. Stain bleaching by manganese complexes with 1,4,7-triazacyclononane-based ligands; 3.2. Raw cotton bleaching; 3.2.1. General; 3.2.2. Manganese complexes containing 1,4,7-triazacyclononane ligands; 3.3. Wood pulp bleaching; 3.3.1. General; 3.3.2. Bleach catalysts; 4. Paint Drying; 5. Conclusions; References
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Chapter Four: Green Challenges of Catalysis via Iron(IV)oxo and Iron(V)oxo Species1. Introduction; 2. Iron(IV)oxo Complexes; 3. A Race for Iron(V)oxo Molecules; 3.1. Spectral characterization of iron(V)oxo compounds; 3.2. Reactivity of iron(V)oxo complexes; 4. Oxidative Catalysis in Aqueous Environment; 4.1. Guiding strategies; 4.2. Catalyzed oxidations by hydrogen peroxide in water; 4.3. Second generation of TAML activators; 4.4. Problems associated with environmentally relevant catalysis; 4.5. Novel applications of TAML activators
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5. Back to Nature or Metal-Organic Framework Instead of a Protein Coat?5.1. Protection of oxidation catalyst by biomolecules; 5.2. Metal-organic materials; 6. Concluding Remarks; Acknowledgments; References; Chapter Five: Manganese Compounds as Versatile Catalysts for the Oxidative Degradation of Organic Dyes; 1. Introduction; 2. Metal Ion-Catalyzed Oxidative Dye Degradation by H2O2; 2.1. General observations; 2.2. Complex formation between bicarbonate and Mn(II); 2.3. Complex formation between dye and Mn(II); 2.4. Mn(II)+H2O2/HCO3-: Intermediates in the absence of dye substrate
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2.5. Kinetic investigations
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English
Weitere Ausg.:
ISBN 9780124045828
Weitere Ausg.:
ISBN 0124045820
Sprache:
Englisch
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