Kooperativer Bibliotheksverbund

UID:

Format: 1 online resource (1,128 pages) : , illustrations

ISBN: 0-12-804185-4 , 0-12-804170-6

Note: Front Cover -- Advanced and Emerging Polybenzoxazine Science and Technology -- Copyright -- Dedication -- Contents -- Contributors -- Preface -- Part I: Synthesis and Properties of Benzoxazine Resins -- Chapter 1: Various Synthetic Methods of Benzoxazine Monomers -- 1. Introduction -- 2. Various Synthetic Methods Used for Benzoxazine Synthesis -- 2.1. Mannich-Condensation Based Benzoxazine Synthesis -- 2.1.1. One-pot Benzoxazine Synthesis -- 2.1.2. Benzoxazine Synthesis via Ortho-Hydroxybenzylamine Structure -- 2.1.3. Polycyclic Benzoxazine Synthesis via N, O-Acetal Forming Reaction -- 2.2. Benzoxazine Synthesis via Cycloaddition -- 2.3. Other Reactions for Benzoxazine Synthesis -- 2.4. Benzoxazine Synthesis With Alternative Energy Sources -- 2.5. Synthesis of Naphthoxazine, Benzoxazine Analogue -- 3. Conclusion -- References -- Chapter 2: Catalytic Accelerated Polymerization of Benzoxazines and Their Mechanistic Considerations -- 1. Introduction -- 2. Benzoxazine Polymerization Mechanism Consideration -- 3. Catalysts for Accelerated Benzoxazine Polymerization -- 3.1. Acidic Catalysts -- 3.2. Basic Catalysts -- 4. Catalyst Effects on Polymerization Mechanism and Network Structures -- 4.1. Pure Benzoxazines -- 4.2. Benzoxazine-Epoxy Blends -- 5. Conclusion -- References -- Chapter 3: Molecular Designs of Benzoxazines With Enhanced Reactivity Based on Utilization of Neighboring-Group Participa ... -- 1. Introduction -- 2. Benzoxazines Activated by Neighboring-Group Participation -- 2.1. Neighboring-Group Participation of Polar Substituents -- 2.1.1. Neighboring-Group Participation of a Hydroxyl Group -- 2.1.2. Neighboring-Group Participation of a Carboxylate Group -- 2.2. Neighboring-Group Participation of an Allyl Group -- 3. Benzoxazines Activated by a Thioether Group -- 4. Conclusion -- 5. Experimental -- 5.1. Materials -- 5.2. Analyses. , 5.3. Synthesis of Benzoxazines -- 5.3.1. C-he (Benzoxazine Bearing a Hydroxyl Group) -- 5.3.2. C-tbagl (Benzoxazine Bearing a Carboxylate Group) -- 5.3.3. DHPDS-a (Bifunctional Benzoxazine Bearing a Disulfide Linkage) -- 5.3.4. PHPTP-a -- 5.3.5. ECE-SP-a -- References -- Chapter 4: Development of New Generation Benzoxazine Thermosets Based on Smart Ortho-Benzoxazine Chemistry -- 1. Introduction -- 2. Anomalous Isomeric Effects on the Properties of Bisphenol F-Based Benzoxazines -- 3. Benzoxazole Resin: A Novel Class of Thermoset via Smart Ortho-Benzoxazine Chemistry -- 3.1. Benzoxazole Resin via Ortho-Amide Functional Benzoxazine -- 3.2. Benzoxazole Resin via Ortho-Imide Functional Benzoxazine -- 3.3. Benzoxazole Resin via Ortho-(Amide-Imide) Functional Benzoxazine -- 4. An Ultrahigh Performance Crosslinked PBO via Thermal Conversion From Main-Chain Type Poly(Benzoxazine Amic Acid) -- 5. Thermally Stable Polybenzoxazine via Ortho-Norbornene Functional Benzoxazine Monomers -- 6. Molecular Understanding of the Unexpected Properties of Ortho-Functional Benzoxazine Resins -- 6.1. Benzoxazine Chemistry at the Molecular Level -- 6.2. Model Compounds -- 6.3. Exploiting the Complementarity of the NMR Techniques -- 6.4. Interpreting Electronic Effects -- 6.5. Conclusion at the Molecular Level -- 7. Conclusion -- References -- Chapter 5: Tailoring Polybenzoxazine Chemical Structure: Synthetic Approaches to Flexible Systems -- 1. Introduction -- 2. Benzoxazine Monomers Containing Flexible Segments -- 3. Benzoxazine Oligomers and Polymers Containing Flexible Spacers -- 4. Conclusion -- References -- Chapter 6: 3,4-Dihydro-1,3-2H-Benzoxazines: Uses Other Than Making Polybenzoxazines -- 1. Introduction -- 2. Novel Luminescent Properties -- 3. Novel Ligands for Metal Ions -- 4. Nanoceria from Cerium-Benzoxazine Complexes. , 5. Novel Reducing Agents Through One Electron-Donation Mechanism -- 6. Nanometallic Silver-Coating Application -- 7. Conclusion -- References -- Chapter 7: Symmetric Versus Asymmetric di-Bz Monomer Design: Structure-to-Properties Relationship -- 1. Introduction -- 2. State of the Art of Symmetric di-Bz Monomers -- 2.1. Class A di-Bz -- 2.1.1. Electron Donating and Withdrawing Effects -- 2.1.2. Flexibility of the Bridging Group -- 2.1.3. Monomers With Additional Functionality -- 2.2. Class B di-BZ -- 2.2.1. Flexibility of the Bridging Diamine -- 2.2.2. Functional Phenols -- 2.2.3. Naturally Occurring Phenolic Compounds -- 3. Asymmetric Benzoxazines -- 4. Conclusion -- Bibliography -- Part II: Physical and Chemical Properties of Cross-linked Polybenzoxazines -- Chapter 8: Modern Developments Using Molecular Simulation to Predict the Physical and Mechanical Properties of Polybenzox ... -- 1. Introduction: The Rationale for Using Molecular Simulation -- 2. The Methodology for Building a Realistic Structure for MM and MD Simulations -- 3. Calculation of Physical and Mechanical Properties for Polybenzoxazines using MM Techniques -- 4. Using MM Techniques to Examine the Influence of Hydrogen bonding in the Benzoxazine Structure -- 5. The Methodology of MD Simulations -- 6. Comparison of Mechanical Properties -- 7. Calculation of Physical Properties for Oligomeric and Telechelic Polybenzoxazines using MD Techniques -- 8. Conclusions -- 9. Materials and Methods -- 9.1. Thermal Analysis of monomers, blends, oligomers, and cured polybenzoxazines -- 9.2. Computational Hardware -- Acknowledgments -- References -- Chapter 9: Predictive Methodology and Properties of Polybenzoxazines -- 1. Introduction -- 2. Basis of QSPR -- 3. Current Applications of QSPR -- 4. Glass Transition Temperature of Polybenzoxazines -- 4.1. Effect of Initiators. , 4.2. Tg of Polybenzoxazines -- 5. Char Yield -- 5.1. Char Yield From Five Monomers -- 5.2. Char Yield From 32 Monomers -- 6. Conclusions -- Acknowledgments -- References -- Chapter 10: Properties Enhancement Obtained in Anhydride-Modified Polybenzoxazines: Effects of Ester Functional Group on ... -- 1. Introduction -- 2. Aromatic Ester and Amide Linkage Formation in Polybenzoxazine Alloyed With Poly(Amic Acid) -- 2.1. Spectroscopic Evidence of Aromatic Ester and Amide Linkage Formation in Polybenzoxazine Network -- 2.2. Important Characteristics of Polybenzoxazine/Poly(Amic Acid) Alloy Networks -- 3. Anhydride-Modified Polybenzoxazine: An Introduction of Ester Linkages in Polybenzoxazine Network [26] -- 3.1. Spectroscopic Evidence of the Formation of Aromatic Ester Linkage in Anhydride-Modified Polybenzoxazine -- 3.2. Network Formation by Thermal Cure of Poly(BA-a)/BTDA Copolymers -- 3.3. Dynamic Mechanical Properties of BTDA-Modified Polybenzoxazine -- 3.4. Nanoindentation Behaviors Of Poly(BA-a)/BTDA Copolymer -- 3.5. Thermal Stability Investigation of Poly(BA-a)/BTDA Copolymers -- 4. Investigation of Types of Dianhydrides on Properties of Dianhydride-Modified Polybenzoxazine [27] -- 4.1. Network Formation by Thermal Cure of Poly(BA-a):Dianhydride Copolymers -- 4.2. Mechanical Characteristics of Aromatic Carboxylic Dianhydride-Modified Polybenzoxazine -- 4.3. Dynamic Mechanical Properties of Poly(BA-a):Diandydride Copolymers -- 4.4. Thermal Stability of Poly(BA-a):Dianhydride Copolymers -- 4.5. Characteristics of Polybenzoxazine Modified With Isomeric Biphenyltetracarboxylic Dianhydrides [28] -- 5. Effects of Monoanhydrides and Dianhydrides on Properties of Polybenzoxazine [31] -- 5.1. Superior Thermal Properties Obtained in Dianhydride-Modified Polybenzoxazine -- 5.2. Toughness Enhancement Observed in Monoanhydride-Modified Polybenzoxazine. , 6. Enhanced Fire Resistance and Thermomechanical Properties Obtained in Dianhydride-Modified Polybenzoxazine Reinforced W ... -- 6.1. Fire-Resistant Behaviors of Carbon Fiber-Reinforced Composites From Dianhydride-Modified Polybenzoxazine Matrix -- 6.2. High Reinforcing Effect of Carbon Fiber in Dianhydride-Modified Polybenzoxazine -- 7. Future Work -- 8. Conclusions -- Acknowledgments -- References -- Chapter 11: Thermal Degradation Mechanism of Polybenzoxazines -- 1. Introduction -- 2. Thermal Degradation of Benzoxazine Models -- 3. Thermal Degradation Mechanism of Polybenzoxazine Homopolymers -- 3.1. With Different Amines -- 3.2. With Different Phenols -- 3.3. With Different Linkages -- 3.4. With Comparable Structures -- 4. Thermal Degradation Mechanism of Polybenzoxazines With Functional Groups -- 5. Thermal Degradation Mechanism of Blends Based on Polybenzoxazines -- 5.1. The Copolymers Based on Benzoxazines -- 5.2. The Copolymerized Structures of Benzoxazine as Main Chain or End Group -- 5.3. The Blends Based on Polybenzoxazine and Others -- 6. Conclusions -- Acknowledgments -- References -- Chapter 12: Mediated Surface Properties of Polybenzoxazines -- 1. Introduction -- 2. Surface Properties of Polybenzoxazines -- 2.1. Low-Surface-Free-Energy Materials Based on Polybenzoxazines -- 2.2. Durable Resistance Applications of Polybenzoxazines -- 2.3. Tuning the Surface Properties of Polybenzoxazines Thin Film -- 2.4. Superhydrophobic Surfaces -- 2.4.1. Polybenzoxazine/SiO2 Hybrid Superhydrophobic Surfaces -- 2.4.2. Polybenzoxazine/Carbon Nanotube Hybrid Superhydrophobic Surfaces -- 3. Conclusions -- References -- Part III: Application of Advanced Organic Synthesis for Benzoxazine Resins -- Chapter 13: Thiol-Benzoxazine Chemistry for Macromolecular Modifications -- 1. Introduction. , 2. Thiol-Benzoxazine Reaction in Polymer Synthesis and Modification.

Language: English

UID:

Format: 1 online resource (1,128 pages) : , illustrations

ISBN: 0-12-804185-4 , 0-12-804170-6

Note: Front Cover -- Advanced and Emerging Polybenzoxazine Science and Technology -- Copyright -- Dedication -- Contents -- Contributors -- Preface -- Part I: Synthesis and Properties of Benzoxazine Resins -- Chapter 1: Various Synthetic Methods of Benzoxazine Monomers -- 1. Introduction -- 2. Various Synthetic Methods Used for Benzoxazine Synthesis -- 2.1. Mannich-Condensation Based Benzoxazine Synthesis -- 2.1.1. One-pot Benzoxazine Synthesis -- 2.1.2. Benzoxazine Synthesis via Ortho-Hydroxybenzylamine Structure -- 2.1.3. Polycyclic Benzoxazine Synthesis via N, O-Acetal Forming Reaction -- 2.2. Benzoxazine Synthesis via Cycloaddition -- 2.3. Other Reactions for Benzoxazine Synthesis -- 2.4. Benzoxazine Synthesis With Alternative Energy Sources -- 2.5. Synthesis of Naphthoxazine, Benzoxazine Analogue -- 3. Conclusion -- References -- Chapter 2: Catalytic Accelerated Polymerization of Benzoxazines and Their Mechanistic Considerations -- 1. Introduction -- 2. Benzoxazine Polymerization Mechanism Consideration -- 3. Catalysts for Accelerated Benzoxazine Polymerization -- 3.1. Acidic Catalysts -- 3.2. Basic Catalysts -- 4. Catalyst Effects on Polymerization Mechanism and Network Structures -- 4.1. Pure Benzoxazines -- 4.2. Benzoxazine-Epoxy Blends -- 5. Conclusion -- References -- Chapter 3: Molecular Designs of Benzoxazines With Enhanced Reactivity Based on Utilization of Neighboring-Group Participa ... -- 1. Introduction -- 2. Benzoxazines Activated by Neighboring-Group Participation -- 2.1. Neighboring-Group Participation of Polar Substituents -- 2.1.1. Neighboring-Group Participation of a Hydroxyl Group -- 2.1.2. Neighboring-Group Participation of a Carboxylate Group -- 2.2. Neighboring-Group Participation of an Allyl Group -- 3. Benzoxazines Activated by a Thioether Group -- 4. Conclusion -- 5. Experimental -- 5.1. Materials -- 5.2. Analyses. , 5.3. Synthesis of Benzoxazines -- 5.3.1. C-he (Benzoxazine Bearing a Hydroxyl Group) -- 5.3.2. C-tbagl (Benzoxazine Bearing a Carboxylate Group) -- 5.3.3. DHPDS-a (Bifunctional Benzoxazine Bearing a Disulfide Linkage) -- 5.3.4. PHPTP-a -- 5.3.5. ECE-SP-a -- References -- Chapter 4: Development of New Generation Benzoxazine Thermosets Based on Smart Ortho-Benzoxazine Chemistry -- 1. Introduction -- 2. Anomalous Isomeric Effects on the Properties of Bisphenol F-Based Benzoxazines -- 3. Benzoxazole Resin: A Novel Class of Thermoset via Smart Ortho-Benzoxazine Chemistry -- 3.1. Benzoxazole Resin via Ortho-Amide Functional Benzoxazine -- 3.2. Benzoxazole Resin via Ortho-Imide Functional Benzoxazine -- 3.3. Benzoxazole Resin via Ortho-(Amide-Imide) Functional Benzoxazine -- 4. An Ultrahigh Performance Crosslinked PBO via Thermal Conversion From Main-Chain Type Poly(Benzoxazine Amic Acid) -- 5. Thermally Stable Polybenzoxazine via Ortho-Norbornene Functional Benzoxazine Monomers -- 6. Molecular Understanding of the Unexpected Properties of Ortho-Functional Benzoxazine Resins -- 6.1. Benzoxazine Chemistry at the Molecular Level -- 6.2. Model Compounds -- 6.3. Exploiting the Complementarity of the NMR Techniques -- 6.4. Interpreting Electronic Effects -- 6.5. Conclusion at the Molecular Level -- 7. Conclusion -- References -- Chapter 5: Tailoring Polybenzoxazine Chemical Structure: Synthetic Approaches to Flexible Systems -- 1. Introduction -- 2. Benzoxazine Monomers Containing Flexible Segments -- 3. Benzoxazine Oligomers and Polymers Containing Flexible Spacers -- 4. Conclusion -- References -- Chapter 6: 3,4-Dihydro-1,3-2H-Benzoxazines: Uses Other Than Making Polybenzoxazines -- 1. Introduction -- 2. Novel Luminescent Properties -- 3. Novel Ligands for Metal Ions -- 4. Nanoceria from Cerium-Benzoxazine Complexes. , 5. Novel Reducing Agents Through One Electron-Donation Mechanism -- 6. Nanometallic Silver-Coating Application -- 7. Conclusion -- References -- Chapter 7: Symmetric Versus Asymmetric di-Bz Monomer Design: Structure-to-Properties Relationship -- 1. Introduction -- 2. State of the Art of Symmetric di-Bz Monomers -- 2.1. Class A di-Bz -- 2.1.1. Electron Donating and Withdrawing Effects -- 2.1.2. Flexibility of the Bridging Group -- 2.1.3. Monomers With Additional Functionality -- 2.2. Class B di-BZ -- 2.2.1. Flexibility of the Bridging Diamine -- 2.2.2. Functional Phenols -- 2.2.3. Naturally Occurring Phenolic Compounds -- 3. Asymmetric Benzoxazines -- 4. Conclusion -- Bibliography -- Part II: Physical and Chemical Properties of Cross-linked Polybenzoxazines -- Chapter 8: Modern Developments Using Molecular Simulation to Predict the Physical and Mechanical Properties of Polybenzox ... -- 1. Introduction: The Rationale for Using Molecular Simulation -- 2. The Methodology for Building a Realistic Structure for MM and MD Simulations -- 3. Calculation of Physical and Mechanical Properties for Polybenzoxazines using MM Techniques -- 4. Using MM Techniques to Examine the Influence of Hydrogen bonding in the Benzoxazine Structure -- 5. The Methodology of MD Simulations -- 6. Comparison of Mechanical Properties -- 7. Calculation of Physical Properties for Oligomeric and Telechelic Polybenzoxazines using MD Techniques -- 8. Conclusions -- 9. Materials and Methods -- 9.1. Thermal Analysis of monomers, blends, oligomers, and cured polybenzoxazines -- 9.2. Computational Hardware -- Acknowledgments -- References -- Chapter 9: Predictive Methodology and Properties of Polybenzoxazines -- 1. Introduction -- 2. Basis of QSPR -- 3. Current Applications of QSPR -- 4. Glass Transition Temperature of Polybenzoxazines -- 4.1. Effect of Initiators. , 4.2. Tg of Polybenzoxazines -- 5. Char Yield -- 5.1. Char Yield From Five Monomers -- 5.2. Char Yield From 32 Monomers -- 6. Conclusions -- Acknowledgments -- References -- Chapter 10: Properties Enhancement Obtained in Anhydride-Modified Polybenzoxazines: Effects of Ester Functional Group on ... -- 1. Introduction -- 2. Aromatic Ester and Amide Linkage Formation in Polybenzoxazine Alloyed With Poly(Amic Acid) -- 2.1. Spectroscopic Evidence of Aromatic Ester and Amide Linkage Formation in Polybenzoxazine Network -- 2.2. Important Characteristics of Polybenzoxazine/Poly(Amic Acid) Alloy Networks -- 3. Anhydride-Modified Polybenzoxazine: An Introduction of Ester Linkages in Polybenzoxazine Network [26] -- 3.1. Spectroscopic Evidence of the Formation of Aromatic Ester Linkage in Anhydride-Modified Polybenzoxazine -- 3.2. Network Formation by Thermal Cure of Poly(BA-a)/BTDA Copolymers -- 3.3. Dynamic Mechanical Properties of BTDA-Modified Polybenzoxazine -- 3.4. Nanoindentation Behaviors Of Poly(BA-a)/BTDA Copolymer -- 3.5. Thermal Stability Investigation of Poly(BA-a)/BTDA Copolymers -- 4. Investigation of Types of Dianhydrides on Properties of Dianhydride-Modified Polybenzoxazine [27] -- 4.1. Network Formation by Thermal Cure of Poly(BA-a):Dianhydride Copolymers -- 4.2. Mechanical Characteristics of Aromatic Carboxylic Dianhydride-Modified Polybenzoxazine -- 4.3. Dynamic Mechanical Properties of Poly(BA-a):Diandydride Copolymers -- 4.4. Thermal Stability of Poly(BA-a):Dianhydride Copolymers -- 4.5. Characteristics of Polybenzoxazine Modified With Isomeric Biphenyltetracarboxylic Dianhydrides [28] -- 5. Effects of Monoanhydrides and Dianhydrides on Properties of Polybenzoxazine [31] -- 5.1. Superior Thermal Properties Obtained in Dianhydride-Modified Polybenzoxazine -- 5.2. Toughness Enhancement Observed in Monoanhydride-Modified Polybenzoxazine. , 6. Enhanced Fire Resistance and Thermomechanical Properties Obtained in Dianhydride-Modified Polybenzoxazine Reinforced W ... -- 6.1. Fire-Resistant Behaviors of Carbon Fiber-Reinforced Composites From Dianhydride-Modified Polybenzoxazine Matrix -- 6.2. High Reinforcing Effect of Carbon Fiber in Dianhydride-Modified Polybenzoxazine -- 7. Future Work -- 8. Conclusions -- Acknowledgments -- References -- Chapter 11: Thermal Degradation Mechanism of Polybenzoxazines -- 1. Introduction -- 2. Thermal Degradation of Benzoxazine Models -- 3. Thermal Degradation Mechanism of Polybenzoxazine Homopolymers -- 3.1. With Different Amines -- 3.2. With Different Phenols -- 3.3. With Different Linkages -- 3.4. With Comparable Structures -- 4. Thermal Degradation Mechanism of Polybenzoxazines With Functional Groups -- 5. Thermal Degradation Mechanism of Blends Based on Polybenzoxazines -- 5.1. The Copolymers Based on Benzoxazines -- 5.2. The Copolymerized Structures of Benzoxazine as Main Chain or End Group -- 5.3. The Blends Based on Polybenzoxazine and Others -- 6. Conclusions -- Acknowledgments -- References -- Chapter 12: Mediated Surface Properties of Polybenzoxazines -- 1. Introduction -- 2. Surface Properties of Polybenzoxazines -- 2.1. Low-Surface-Free-Energy Materials Based on Polybenzoxazines -- 2.2. Durable Resistance Applications of Polybenzoxazines -- 2.3. Tuning the Surface Properties of Polybenzoxazines Thin Film -- 2.4. Superhydrophobic Surfaces -- 2.4.1. Polybenzoxazine/SiO2 Hybrid Superhydrophobic Surfaces -- 2.4.2. Polybenzoxazine/Carbon Nanotube Hybrid Superhydrophobic Surfaces -- 3. Conclusions -- References -- Part III: Application of Advanced Organic Synthesis for Benzoxazine Resins -- Chapter 13: Thiol-Benzoxazine Chemistry for Macromolecular Modifications -- 1. Introduction. , 2. Thiol-Benzoxazine Reaction in Polymer Synthesis and Modification.

Language: English

UID:

Format: 1 online resource (1,128 pages) : , illustrations

ISBN: 0-12-804185-4 , 0-12-804170-6

Note: Front Cover -- Advanced and Emerging Polybenzoxazine Science and Technology -- Copyright -- Dedication -- Contents -- Contributors -- Preface -- Part I: Synthesis and Properties of Benzoxazine Resins -- Chapter 1: Various Synthetic Methods of Benzoxazine Monomers -- 1. Introduction -- 2. Various Synthetic Methods Used for Benzoxazine Synthesis -- 2.1. Mannich-Condensation Based Benzoxazine Synthesis -- 2.1.1. One-pot Benzoxazine Synthesis -- 2.1.2. Benzoxazine Synthesis via Ortho-Hydroxybenzylamine Structure -- 2.1.3. Polycyclic Benzoxazine Synthesis via N, O-Acetal Forming Reaction -- 2.2. Benzoxazine Synthesis via Cycloaddition -- 2.3. Other Reactions for Benzoxazine Synthesis -- 2.4. Benzoxazine Synthesis With Alternative Energy Sources -- 2.5. Synthesis of Naphthoxazine, Benzoxazine Analogue -- 3. Conclusion -- References -- Chapter 2: Catalytic Accelerated Polymerization of Benzoxazines and Their Mechanistic Considerations -- 1. Introduction -- 2. Benzoxazine Polymerization Mechanism Consideration -- 3. Catalysts for Accelerated Benzoxazine Polymerization -- 3.1. Acidic Catalysts -- 3.2. Basic Catalysts -- 4. Catalyst Effects on Polymerization Mechanism and Network Structures -- 4.1. Pure Benzoxazines -- 4.2. Benzoxazine-Epoxy Blends -- 5. Conclusion -- References -- Chapter 3: Molecular Designs of Benzoxazines With Enhanced Reactivity Based on Utilization of Neighboring-Group Participa ... -- 1. Introduction -- 2. Benzoxazines Activated by Neighboring-Group Participation -- 2.1. Neighboring-Group Participation of Polar Substituents -- 2.1.1. Neighboring-Group Participation of a Hydroxyl Group -- 2.1.2. Neighboring-Group Participation of a Carboxylate Group -- 2.2. Neighboring-Group Participation of an Allyl Group -- 3. Benzoxazines Activated by a Thioether Group -- 4. Conclusion -- 5. Experimental -- 5.1. Materials -- 5.2. Analyses. , 5.3. Synthesis of Benzoxazines -- 5.3.1. C-he (Benzoxazine Bearing a Hydroxyl Group) -- 5.3.2. C-tbagl (Benzoxazine Bearing a Carboxylate Group) -- 5.3.3. DHPDS-a (Bifunctional Benzoxazine Bearing a Disulfide Linkage) -- 5.3.4. PHPTP-a -- 5.3.5. ECE-SP-a -- References -- Chapter 4: Development of New Generation Benzoxazine Thermosets Based on Smart Ortho-Benzoxazine Chemistry -- 1. Introduction -- 2. Anomalous Isomeric Effects on the Properties of Bisphenol F-Based Benzoxazines -- 3. Benzoxazole Resin: A Novel Class of Thermoset via Smart Ortho-Benzoxazine Chemistry -- 3.1. Benzoxazole Resin via Ortho-Amide Functional Benzoxazine -- 3.2. Benzoxazole Resin via Ortho-Imide Functional Benzoxazine -- 3.3. Benzoxazole Resin via Ortho-(Amide-Imide) Functional Benzoxazine -- 4. An Ultrahigh Performance Crosslinked PBO via Thermal Conversion From Main-Chain Type Poly(Benzoxazine Amic Acid) -- 5. Thermally Stable Polybenzoxazine via Ortho-Norbornene Functional Benzoxazine Monomers -- 6. Molecular Understanding of the Unexpected Properties of Ortho-Functional Benzoxazine Resins -- 6.1. Benzoxazine Chemistry at the Molecular Level -- 6.2. Model Compounds -- 6.3. Exploiting the Complementarity of the NMR Techniques -- 6.4. Interpreting Electronic Effects -- 6.5. Conclusion at the Molecular Level -- 7. Conclusion -- References -- Chapter 5: Tailoring Polybenzoxazine Chemical Structure: Synthetic Approaches to Flexible Systems -- 1. Introduction -- 2. Benzoxazine Monomers Containing Flexible Segments -- 3. Benzoxazine Oligomers and Polymers Containing Flexible Spacers -- 4. Conclusion -- References -- Chapter 6: 3,4-Dihydro-1,3-2H-Benzoxazines: Uses Other Than Making Polybenzoxazines -- 1. Introduction -- 2. Novel Luminescent Properties -- 3. Novel Ligands for Metal Ions -- 4. Nanoceria from Cerium-Benzoxazine Complexes. , 5. Novel Reducing Agents Through One Electron-Donation Mechanism -- 6. Nanometallic Silver-Coating Application -- 7. Conclusion -- References -- Chapter 7: Symmetric Versus Asymmetric di-Bz Monomer Design: Structure-to-Properties Relationship -- 1. Introduction -- 2. State of the Art of Symmetric di-Bz Monomers -- 2.1. Class A di-Bz -- 2.1.1. Electron Donating and Withdrawing Effects -- 2.1.2. Flexibility of the Bridging Group -- 2.1.3. Monomers With Additional Functionality -- 2.2. Class B di-BZ -- 2.2.1. Flexibility of the Bridging Diamine -- 2.2.2. Functional Phenols -- 2.2.3. Naturally Occurring Phenolic Compounds -- 3. Asymmetric Benzoxazines -- 4. Conclusion -- Bibliography -- Part II: Physical and Chemical Properties of Cross-linked Polybenzoxazines -- Chapter 8: Modern Developments Using Molecular Simulation to Predict the Physical and Mechanical Properties of Polybenzox ... -- 1. Introduction: The Rationale for Using Molecular Simulation -- 2. The Methodology for Building a Realistic Structure for MM and MD Simulations -- 3. Calculation of Physical and Mechanical Properties for Polybenzoxazines using MM Techniques -- 4. Using MM Techniques to Examine the Influence of Hydrogen bonding in the Benzoxazine Structure -- 5. The Methodology of MD Simulations -- 6. Comparison of Mechanical Properties -- 7. Calculation of Physical Properties for Oligomeric and Telechelic Polybenzoxazines using MD Techniques -- 8. Conclusions -- 9. Materials and Methods -- 9.1. Thermal Analysis of monomers, blends, oligomers, and cured polybenzoxazines -- 9.2. Computational Hardware -- Acknowledgments -- References -- Chapter 9: Predictive Methodology and Properties of Polybenzoxazines -- 1. Introduction -- 2. Basis of QSPR -- 3. Current Applications of QSPR -- 4. Glass Transition Temperature of Polybenzoxazines -- 4.1. Effect of Initiators. , 4.2. Tg of Polybenzoxazines -- 5. Char Yield -- 5.1. Char Yield From Five Monomers -- 5.2. Char Yield From 32 Monomers -- 6. Conclusions -- Acknowledgments -- References -- Chapter 10: Properties Enhancement Obtained in Anhydride-Modified Polybenzoxazines: Effects of Ester Functional Group on ... -- 1. Introduction -- 2. Aromatic Ester and Amide Linkage Formation in Polybenzoxazine Alloyed With Poly(Amic Acid) -- 2.1. Spectroscopic Evidence of Aromatic Ester and Amide Linkage Formation in Polybenzoxazine Network -- 2.2. Important Characteristics of Polybenzoxazine/Poly(Amic Acid) Alloy Networks -- 3. Anhydride-Modified Polybenzoxazine: An Introduction of Ester Linkages in Polybenzoxazine Network [26] -- 3.1. Spectroscopic Evidence of the Formation of Aromatic Ester Linkage in Anhydride-Modified Polybenzoxazine -- 3.2. Network Formation by Thermal Cure of Poly(BA-a)/BTDA Copolymers -- 3.3. Dynamic Mechanical Properties of BTDA-Modified Polybenzoxazine -- 3.4. Nanoindentation Behaviors Of Poly(BA-a)/BTDA Copolymer -- 3.5. Thermal Stability Investigation of Poly(BA-a)/BTDA Copolymers -- 4. Investigation of Types of Dianhydrides on Properties of Dianhydride-Modified Polybenzoxazine [27] -- 4.1. Network Formation by Thermal Cure of Poly(BA-a):Dianhydride Copolymers -- 4.2. Mechanical Characteristics of Aromatic Carboxylic Dianhydride-Modified Polybenzoxazine -- 4.3. Dynamic Mechanical Properties of Poly(BA-a):Diandydride Copolymers -- 4.4. Thermal Stability of Poly(BA-a):Dianhydride Copolymers -- 4.5. Characteristics of Polybenzoxazine Modified With Isomeric Biphenyltetracarboxylic Dianhydrides [28] -- 5. Effects of Monoanhydrides and Dianhydrides on Properties of Polybenzoxazine [31] -- 5.1. Superior Thermal Properties Obtained in Dianhydride-Modified Polybenzoxazine -- 5.2. Toughness Enhancement Observed in Monoanhydride-Modified Polybenzoxazine. , 6. Enhanced Fire Resistance and Thermomechanical Properties Obtained in Dianhydride-Modified Polybenzoxazine Reinforced W ... -- 6.1. Fire-Resistant Behaviors of Carbon Fiber-Reinforced Composites From Dianhydride-Modified Polybenzoxazine Matrix -- 6.2. High Reinforcing Effect of Carbon Fiber in Dianhydride-Modified Polybenzoxazine -- 7. Future Work -- 8. Conclusions -- Acknowledgments -- References -- Chapter 11: Thermal Degradation Mechanism of Polybenzoxazines -- 1. Introduction -- 2. Thermal Degradation of Benzoxazine Models -- 3. Thermal Degradation Mechanism of Polybenzoxazine Homopolymers -- 3.1. With Different Amines -- 3.2. With Different Phenols -- 3.3. With Different Linkages -- 3.4. With Comparable Structures -- 4. Thermal Degradation Mechanism of Polybenzoxazines With Functional Groups -- 5. Thermal Degradation Mechanism of Blends Based on Polybenzoxazines -- 5.1. The Copolymers Based on Benzoxazines -- 5.2. The Copolymerized Structures of Benzoxazine as Main Chain or End Group -- 5.3. The Blends Based on Polybenzoxazine and Others -- 6. Conclusions -- Acknowledgments -- References -- Chapter 12: Mediated Surface Properties of Polybenzoxazines -- 1. Introduction -- 2. Surface Properties of Polybenzoxazines -- 2.1. Low-Surface-Free-Energy Materials Based on Polybenzoxazines -- 2.2. Durable Resistance Applications of Polybenzoxazines -- 2.3. Tuning the Surface Properties of Polybenzoxazines Thin Film -- 2.4. Superhydrophobic Surfaces -- 2.4.1. Polybenzoxazine/SiO2 Hybrid Superhydrophobic Surfaces -- 2.4.2. Polybenzoxazine/Carbon Nanotube Hybrid Superhydrophobic Surfaces -- 3. Conclusions -- References -- Part III: Application of Advanced Organic Synthesis for Benzoxazine Resins -- Chapter 13: Thiol-Benzoxazine Chemistry for Macromolecular Modifications -- 1. Introduction. , 2. Thiol-Benzoxazine Reaction in Polymer Synthesis and Modification.

Language: English

UID:

Format: 1 online resource (xv, 573 pages) : , illustrations (some color)

Edition: Second edition.

ISBN: 0-12-804195-1 , 9780128041856

Series Statement: Gale eBooks

Content: This book presents key aspects of soil chemistry in environmental science, including dose responses, risk characterization, and practical applications of calculations using spreadsheets. It offers a holistic, practical approach to the application of environmental chemistry to soil science.

Note: Description based upon print version of record. , ""Front Cover""; ""Soil and Environmental Chemistry""; ""Copyright""; ""Dedication""; ""Contents""; ""Preface""; ""Chapter 1: Elements: Their Origin and Abundance""; ""Dose-Response Distributions""; ""Introduction""; ""A Brief History of the Solar System and Planet Earth""; ""The Composition of Earth's Crust and Soils""; ""The Abundance of Elements in the Solar System, Earth's Crust, and Soils""; ""Elements and Isotopes""; ""Nuclear Binding Energy""; ""Enrichment and Depletion during Planetary Formation""; ""Planetary Accretion""; ""The Rock Cycle""; ""Soil Formation"" , ""Concentration Frequency Distributions of the Elements""""Estimating the Most Probable Concentration and Concentration Range Using the LOGARITHMIC TRANSFORMATION""; ""Summary""; ""Factors Governing Nuclear Stability and Isotope Abundance""; ""The Table of Isotopes and Nuclear Magic Numbers""; ""Nuclear Magic Numbers""; ""Nucleosynthesis""; ""Nuclear Reactions""; ""Nuclear Fusion""; ""Neutron Capture""; ""Cosmic Ray Spallation""; ""Transuranium Elements""; ""Thermonuclear FUSION Cycles""; ""The CNO Cycle""; ""The Triple-Alpha Process""; ""Carbon Burning"" , ""Neutron-Emitting Reactions that Sustain the S-Process""""Random Sequential Dilutions and the Law of Proportionate Effect""; ""The Estimate of Central Tendency and Variation of a Log-Normal Distribution""; ""Chapter 2: Soil Moisture and Hydrology""; ""Introduction""; ""Water Resources and the Hydrologic Cycle""; ""Water Budgets""; ""Residence Time and Runoff Ratios""; ""Groundwater Hydrology""; ""Water in the Porosphere""; ""Hydrologic Units""; ""Darcy's Law""; ""Hydrostatic Heads and Hydrostatic Gradients""; ""Intrinsic Permeability""; ""Groundwater Flow Nets""; ""Vadose Zone Hydrology"" , ""Capillary Forces""""Soil Moisture Zones""; ""The Water Characteristic Curve and Vadose Zone Hydraulic Conductivity""; ""Elementary Solute Transport Models""; ""The Retardation Coefficient Model""; ""Plate Theory: Multiple Sequential Partitioning""; ""Summary""; ""Soil Moisture Recharge and Loss""; ""The Water-Holding Capacity of a Soil Profile""; ""Predicting Capillary Rise""; ""Symbols and Units in the Derivation of the Retardation Coefficient Model of Solute Transport""; ""Symbols and Units in the Derivation of the Plate Theory Model of Solute Transport"" , ""Empirical Water Characteristic Function and Unsaturated Hydraulic Conductivity""""Chapter 3: Clay Mineralogy and Clay Chemistry""; ""Introduction""; ""Mineral Weathering""; ""Mineralogy""; ""The Structure of Layer Silicates""; ""Coordination Polyhedra""; ""The Phyllosilicate Tetrahedral Sheet""; ""The Phyllosilicate Octahedral Sheet""; ""Kaolinite Layer Structure""; ""Talc Layer Structure""; ""Mica-Illite Layer Structure""; ""Chlorite and Hydroxy-Interlayered Smectite Layer Structure""; ""Layer Structure of the Swelling Clay Minerals: Smectite and Vermiculite""; ""Formal Oxidation Numbers"" , ""The Geometry of Pauling's Radius Ratio Rule"" , English

Additional Edition: ISBN 0-12-804178-1

Language: English

UID:

Format: 1 online resource (xv, 573 pages) : , illustrations (some color)

Edition: Second edition.

ISBN: 0-12-804195-1 , 9780128041856

Series Statement: Gale eBooks

Content: This book presents key aspects of soil chemistry in environmental science, including dose responses, risk characterization, and practical applications of calculations using spreadsheets. It offers a holistic, practical approach to the application of environmental chemistry to soil science.

Note: Description based upon print version of record. , ""Front Cover""; ""Soil and Environmental Chemistry""; ""Copyright""; ""Dedication""; ""Contents""; ""Preface""; ""Chapter 1: Elements: Their Origin and Abundance""; ""Dose-Response Distributions""; ""Introduction""; ""A Brief History of the Solar System and Planet Earth""; ""The Composition of Earth's Crust and Soils""; ""The Abundance of Elements in the Solar System, Earth's Crust, and Soils""; ""Elements and Isotopes""; ""Nuclear Binding Energy""; ""Enrichment and Depletion during Planetary Formation""; ""Planetary Accretion""; ""The Rock Cycle""; ""Soil Formation"" , ""Concentration Frequency Distributions of the Elements""""Estimating the Most Probable Concentration and Concentration Range Using the LOGARITHMIC TRANSFORMATION""; ""Summary""; ""Factors Governing Nuclear Stability and Isotope Abundance""; ""The Table of Isotopes and Nuclear Magic Numbers""; ""Nuclear Magic Numbers""; ""Nucleosynthesis""; ""Nuclear Reactions""; ""Nuclear Fusion""; ""Neutron Capture""; ""Cosmic Ray Spallation""; ""Transuranium Elements""; ""Thermonuclear FUSION Cycles""; ""The CNO Cycle""; ""The Triple-Alpha Process""; ""Carbon Burning"" , ""Neutron-Emitting Reactions that Sustain the S-Process""""Random Sequential Dilutions and the Law of Proportionate Effect""; ""The Estimate of Central Tendency and Variation of a Log-Normal Distribution""; ""Chapter 2: Soil Moisture and Hydrology""; ""Introduction""; ""Water Resources and the Hydrologic Cycle""; ""Water Budgets""; ""Residence Time and Runoff Ratios""; ""Groundwater Hydrology""; ""Water in the Porosphere""; ""Hydrologic Units""; ""Darcy's Law""; ""Hydrostatic Heads and Hydrostatic Gradients""; ""Intrinsic Permeability""; ""Groundwater Flow Nets""; ""Vadose Zone Hydrology"" , ""Capillary Forces""""Soil Moisture Zones""; ""The Water Characteristic Curve and Vadose Zone Hydraulic Conductivity""; ""Elementary Solute Transport Models""; ""The Retardation Coefficient Model""; ""Plate Theory: Multiple Sequential Partitioning""; ""Summary""; ""Soil Moisture Recharge and Loss""; ""The Water-Holding Capacity of a Soil Profile""; ""Predicting Capillary Rise""; ""Symbols and Units in the Derivation of the Retardation Coefficient Model of Solute Transport""; ""Symbols and Units in the Derivation of the Plate Theory Model of Solute Transport"" , ""Empirical Water Characteristic Function and Unsaturated Hydraulic Conductivity""""Chapter 3: Clay Mineralogy and Clay Chemistry""; ""Introduction""; ""Mineral Weathering""; ""Mineralogy""; ""The Structure of Layer Silicates""; ""Coordination Polyhedra""; ""The Phyllosilicate Tetrahedral Sheet""; ""The Phyllosilicate Octahedral Sheet""; ""Kaolinite Layer Structure""; ""Talc Layer Structure""; ""Mica-Illite Layer Structure""; ""Chlorite and Hydroxy-Interlayered Smectite Layer Structure""; ""Layer Structure of the Swelling Clay Minerals: Smectite and Vermiculite""; ""Formal Oxidation Numbers"" , ""The Geometry of Pauling's Radius Ratio Rule"" , English

Additional Edition: ISBN 0-12-804178-1

Language: English

UID:

Format: 1 online resource (xv, 573 pages) : , illustrations (some color)

Edition: Second edition.

ISBN: 0-12-804195-1 , 9780128041856

Series Statement: Gale eBooks

Content: This book presents key aspects of soil chemistry in environmental science, including dose responses, risk characterization, and practical applications of calculations using spreadsheets. It offers a holistic, practical approach to the application of environmental chemistry to soil science.

Note: Description based upon print version of record. , ""Front Cover""; ""Soil and Environmental Chemistry""; ""Copyright""; ""Dedication""; ""Contents""; ""Preface""; ""Chapter 1: Elements: Their Origin and Abundance""; ""Dose-Response Distributions""; ""Introduction""; ""A Brief History of the Solar System and Planet Earth""; ""The Composition of Earth's Crust and Soils""; ""The Abundance of Elements in the Solar System, Earth's Crust, and Soils""; ""Elements and Isotopes""; ""Nuclear Binding Energy""; ""Enrichment and Depletion during Planetary Formation""; ""Planetary Accretion""; ""The Rock Cycle""; ""Soil Formation"" , ""Concentration Frequency Distributions of the Elements""""Estimating the Most Probable Concentration and Concentration Range Using the LOGARITHMIC TRANSFORMATION""; ""Summary""; ""Factors Governing Nuclear Stability and Isotope Abundance""; ""The Table of Isotopes and Nuclear Magic Numbers""; ""Nuclear Magic Numbers""; ""Nucleosynthesis""; ""Nuclear Reactions""; ""Nuclear Fusion""; ""Neutron Capture""; ""Cosmic Ray Spallation""; ""Transuranium Elements""; ""Thermonuclear FUSION Cycles""; ""The CNO Cycle""; ""The Triple-Alpha Process""; ""Carbon Burning"" , ""Neutron-Emitting Reactions that Sustain the S-Process""""Random Sequential Dilutions and the Law of Proportionate Effect""; ""The Estimate of Central Tendency and Variation of a Log-Normal Distribution""; ""Chapter 2: Soil Moisture and Hydrology""; ""Introduction""; ""Water Resources and the Hydrologic Cycle""; ""Water Budgets""; ""Residence Time and Runoff Ratios""; ""Groundwater Hydrology""; ""Water in the Porosphere""; ""Hydrologic Units""; ""Darcy's Law""; ""Hydrostatic Heads and Hydrostatic Gradients""; ""Intrinsic Permeability""; ""Groundwater Flow Nets""; ""Vadose Zone Hydrology"" , ""Capillary Forces""""Soil Moisture Zones""; ""The Water Characteristic Curve and Vadose Zone Hydraulic Conductivity""; ""Elementary Solute Transport Models""; ""The Retardation Coefficient Model""; ""Plate Theory: Multiple Sequential Partitioning""; ""Summary""; ""Soil Moisture Recharge and Loss""; ""The Water-Holding Capacity of a Soil Profile""; ""Predicting Capillary Rise""; ""Symbols and Units in the Derivation of the Retardation Coefficient Model of Solute Transport""; ""Symbols and Units in the Derivation of the Plate Theory Model of Solute Transport"" , ""Empirical Water Characteristic Function and Unsaturated Hydraulic Conductivity""""Chapter 3: Clay Mineralogy and Clay Chemistry""; ""Introduction""; ""Mineral Weathering""; ""Mineralogy""; ""The Structure of Layer Silicates""; ""Coordination Polyhedra""; ""The Phyllosilicate Tetrahedral Sheet""; ""The Phyllosilicate Octahedral Sheet""; ""Kaolinite Layer Structure""; ""Talc Layer Structure""; ""Mica-Illite Layer Structure""; ""Chlorite and Hydroxy-Interlayered Smectite Layer Structure""; ""Layer Structure of the Swelling Clay Minerals: Smectite and Vermiculite""; ""Formal Oxidation Numbers"" , ""The Geometry of Pauling's Radius Ratio Rule"" , English

Additional Edition: ISBN 0-12-804178-1

Language: English