UID:
edoccha_9960099781302883
Umfang:
1 online resource (245 pages)
ISBN:
0-12-822092-9
Inhalt:
Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot.
Anmerkung:
Front Cover -- Pincer-Metal Complexes -- Copyright Page -- Contents -- List of contributors -- Foreword -- Preface -- 1 Application of pincer metal complexes in catalytic transformations -- 1.1 Introduction -- 1.2 Dehydrogenation of ammonia borane and its derivatives -- 1.3 Dinitrogen activation using pincer ligands -- 1.3.1 Catalytic dinitrogen activation using Mo pincer catalyst -- 1.3.2 Catalytic dinitrogen activation using 3d metal pincer catalyst -- 1.3.3 Catalytic dinitrogen fixation using earlier transition metals (V, Ti, Zr) -- 1.3.4 N-X bond formation with metal nitride in pincer complexes -- 1.3.5 Catalytic silylation of dinitrogen using transition metal pincer complexes -- 1.4 Pincer complexes as hydrogenation catalyst -- 1.4.1 Ester hydrogenation -- 1.4.2 Amide hydrogenation -- 1.4.3 Hydrogenation of urea, carbamate, carbonate, and imides derivatives -- 1.4.4 Nitrile hydrogenation -- 1.4.5 Hydrogenation of alkynes -- 1.5 Coupling reaction: C-C bond formation reaction -- 1.5.1 Mizoroki-Heck reaction -- 1.5.2 Suzuki-Miyaura reaction -- 1.5.3 Sonogashira, Negishi, Kumada-Corriu, Stille cross-coupling -- 1.6 Redox-Active Pincer Complexes -- 1.7 Conclusion -- References -- 2 Pincer-group(8) and pincer-group(9) metal complexes for catalytic alkane dehydrogenation reactions -- 2.1 Introduction -- 2.1.1 Alkane dehydrogenation -- 2.2 Dehydrogenation reactions of alkane using pincer-Ir complexes -- 2.2.1 Initial reports based on pincer-Ir catalysts -- 2.2.2 Alkane dehydrogenation by PC(sp2)P-Ir systems -- 2.2.3 Alkane dehydrogenation by PYC(sp2)ZP-Ir (Y=O, S, CH2) systems -- 2.2.4 Mechanism of pincer-Ir-catalyzed alkane dehydrogenation -- 2.2.5 Solid/gas-phase alkane dehydrogenation -- 2.2.6 Continuous-flow gas-phase alkane dehydrogenation -- 2.2.7 Alkane dehydrogenation by PC(sp3)P-Ir complexes.
,
2.2.8 Alkane dehydrogenation by POCN-Ir, PBP-Ir, PNP-Ir, and PAlP complexes -- 2.2.9 Alkane dehydrogenation by PXC(sp2)NP-Ir-HCl (X=O, S) complexes -- 2.2.10 Alkane dehydrogenation by non-phosphine-based iridium pincer complexes -- 2.3 Dehydrogenation of alkanes by pincer-metal complexes other than iridium -- 2.3.1 Ruthenium pincer complexes for alkane dehydrogenation -- 2.3.2 Osmium pincer complexes for alkane dehydrogenation -- 2.3.3 Rhodium pincer complexes for alkane dehydrogenation -- 2.4 Applications of alkane dehydrogenation -- 2.4.1 Alkane metathesis -- 2.4.2 Alkane coupling -- 2.4.3 Synthesis of aromatics -- 2.4.3.1 Dehydroaromatization -- 2.4.3.2 Cyclodimerization -- 2.4.3.3 Alkyl group cross metathesis -- 2.4.3.4 Alkyl-aryl coupling -- 2.4.4 Functionalization of alkanes -- 2.4.4.1 Silylation and borylation -- 2.4.4.2 Formylation and aminomethylation -- 2.5 Summary and outlook -- References -- 3 Transition metal-catalyzed dehydrogenation of methanol and related transformations -- 3.1 Introduction -- 3.2 Hydrogen production -- 3.3 N-Methylation reactions -- 3.3.1 N-Methylation of amines -- 3.3.2 N-Methylation of nitro, nitrile, and azide compounds -- 3.3.3 N-Methylation of amides and oximes -- 3.4 N-Formylation reactions -- 3.5 C-Methylation reactions -- 3.5.1 α-Methylation of ketones -- 3.5.2 C-Methylation of alcohols -- 3.5.3 C3-Methylation of indoles -- 3.5.4 α-Methylation of arylacetonitriles -- 3.5.5 Aminomethylations -- 3.6 N-Heterocycles synthesis -- 3.7 Miscellaneous transformations -- 3.8 Conclusion -- References -- 4 Transition metal pincer complexes in acceptorless dehydrogenation reactions -- 4.1 Introduction -- 4.2 Acceptorless dehydrogenation -- 4.2.1 Acceptorless alcohol dehydrogenation -- 4.2.2 Dehydrogenation of alcohols to carboxylic acids -- 4.2.3 Dehydrogenation of amines -- 4.2.4 Dehydrogenation of N-heterocycles.
,
4.3 Conclusion and future perspective -- Acknowledgments -- References -- 5 An outlook on the applications of pincer-metal complexes in catalytic dehydrogenation chemistry -- References -- Index -- Back Cover.
Weitere Ausg.:
Print version: Kumar, Akshai Pincer-Metal Complexes San Diego : Elsevier,c2021 ISBN 9780128220917
Sprache:
Englisch
Bookmarklink
