Kooperativer Bibliotheksverbund

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Format: 1 online resource (392 pages)

ISBN: 0-12-823602-7

Series Statement: Micro and Nano Technologies

Content: "Surface Modified Nanomaterials for Applications in Catalysis: Fundamentals, Methods and Applications provides an overview of the different state-of-the-art surface modification methods of nanomaterials and their commercial applications. The main objective of this book is to comprehensively cover the modification of nanomaterial and their fabrication, including different techniques and discussions of present and emerging commercial applications. The book addresses fundamental chemistry concepts as applied to the modification of nanomaterials for applications in energy, catalysis, water remediation, sensors, and more. Characterization and fabrication methodologies are reviewed, along with the challenges of up-scaling of processes for commercial applications."--

Note: Front Cover -- SURFACE MODIFIED NANOMATERIALS FOR APPLICATIONS IN CATALYSIS -- SURFACE MODIFIED NANOMATERIALS FOR APPLICATIONS IN CATALYSIS: FUNDAMENTALS, METHODS AND APPLICATIONS -- Copyright -- CONTENTS -- Contributors -- About the editors -- Introduction to surface-modified nanomaterials -- REFERENCES -- 1 - New frontiers for heterogeneous catalysis: surface modification of nanomaterials -- 1. Introduction: catalysts, nanomaterials (NMs) and nanocatalysts (NCs) -- 2. Synthetic strategies of NCs -- 3. Need for surface functionalization -- 4. Types of NMs and their functionalization procedures -- 5. Selective applications of surface-functionalized NCs -- 6. Characterization of surface-functionalized NCs -- 7. Topics to be covered in this book -- 8. Summary: present status and future direction -- Abbreviations -- References -- 2 - Fundamental concepts on surface chemistry for nanoparticle modifications -- 1. Introduction -- 1.1 Steric stabilization -- 1.2 Use of silica nanoparticles for the stabilization of nanoparticles -- 1.3 Carbon materials in the stabilization of nanoparticles -- 1.4 Chemical methods of nanoparticle synthesis using various functional surface -- 2. Esterification reaction method -- 3. Phosphate ester method -- 4. In situ modification method -- 5. Conclusions -- References -- 3 - Synthesis of surface-modified nanomaterials -- 1. Introduction -- 2. Nanomaterials surface chemistry and Zeta potential -- 3. Surface modification of catalytic nanoparticles by thermal and plasma treatment -- 4. Silane chemical treatment -- 5. Ligand immobilization techniques to modify catalytic nanoparticles -- 6. Surface modification via single-atom anchoring -- 7. Industrial-scale utilization of synthetic methods to prepare surface-modified nanomaterials -- 8. Challenges, future perspective, and conclusions -- References. , 4 - Surface modification of nano-based catalytic materials for enhanced water treatment applications -- 1. Nanomaterials for water treatment -- 2. Advancement on modification of nanomaterials -- 3. Examples of nanoscale modified catalytic materials -- 3.1 TiO2-based materials -- 3.2 Carbon-based materials for water treatment -- 3.3 NZVI-based materials for water treatment -- 3.3.1 Modification needs and routes of modification of ZVI -- 3.3.2 Surface modifiers -- 3.3.3 Bimetallic particles -- 3.3.4 Sulfidation -- 3.3.5 NZVI supported on various materials -- 3.3.6 Emulsification -- 3.3.7 Combined technologies -- 3.3.8 Examples of water-treatment enhancement of NZVI-based materials -- 4. Conclusions -- Acknowledgment -- References -- 5 - Surface-modified nanomaterials-based catalytic materials for water purification, hydrocarbon production, and po ... -- 1. Introduction -- 2. Nanocatalyst materials -- 3. Wastewater treatment -- 3.1 Zero-valent metal nanocatalysts -- 3.2 Metal oxide nanocatalysts -- 3.2.1 TiO2 -- 3.2.2 Fe2O3 -- 3.2.3 ZnO -- 3.3 Carbon-based nanocatalysts -- 3.3.1 Functionalized graphene-based nanocatalysts -- 3.3.2 Functionalized CNT-based nanocatalysts -- 3.4 Polymer-based nanocatalysts -- 3.5 Miscellaneous nanocatalysts -- 4. Nanocatalysts in hydrocarbon production -- 4.1 Biomass to hydrocarbon -- 4.1.1 Pyrolysis -- 4.1.2 Liquefaction -- 4.1.3 Gasification -- 4.2 CO2 to methanol and other hydrocarbons -- 5. Recent advancement and real-time utilization of nanocatalysts -- 6. Conclusion -- Acknowledgments -- References -- 6 - Surface-modified nanomaterial-based catalytic materials for the production of liquid fuels -- 1. Introduction -- 2. Surface modified nanomaterials (SMNs) for biomass conversion to liquid fuels -- 2.1 Production of 1, 2-propylene glycol and ethylene glycol -- 2.2 Production of 1,4-butanediol. , 2.3 Production of furfural alcohol and related liquid fuels -- 2.4 Production of 5-hydroxymethylfurfural and related liquid derivatives -- 2.5 Production of biodiesel -- 2.6 Production of liquid hydrocarbons -- 3. Surface-modified nanomaterials for the transformation of carbon dioxide to liquid fuels -- 3.1 Reduction of CO2 to methanol -- 3.2 Reduction of CO2 to ethanol -- 3.3 Reduction of CO2 to propanol -- 3.4 Reduction of CO2 to formic acid -- 4. Future perspectives and conclusion -- Acknowledgments -- References -- 7 - SMN-based catalytic membranes for environmental catalysis -- 1. Introduction -- 2. Challenges in SMNs and catalytic MRs -- 3. Types of catalytic membrane reactors (MRs) -- 3.1 Inorganic (silica/metallic) MRs -- 3.2 Organic (polymeric) MRs -- 4. Basic overview of polymeric MRs -- 5. Incorporation of SMNs into polymeric membranes -- 5.1 Methods of SMNs incorporation into polymeric MRs -- 5.1.1 Irradiation-based modifications -- 5.1.1.1 Plasma treatment -- 5.1.1.2 UV-irradiation -- 5.1.2 Grafting-based modifications -- 5.1.2.1 Chemical/electrochemical initiated grafting -- 5.1.2.2 Photoirradiation-induced grafting -- 5.1.2.3 High energy radiation (plasma) induced grafting -- 5.1.3 Surface coating-based modifications -- 5.1.3.1 Gas-phase coatings -- 5.1.3.2 Wet-phase coatings -- 5.2 Characterization methods of SMNs based polymer membranes -- 5.2.1 Advanced microscopic techniques -- 5.2.1.1 Cryo-transmission electron microscopy (cryo-TEM/cryo-EM) -- 5.2.1.2 Atomic force microscopy (AFM) -- 5.2.1.3 Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) -- 5.2.2 X-ray spectroscopic techniques -- 5.2.2.1 X-ray diffraction (XRD) -- 5.2.2.2 X-ray photon correlation spectroscopy (XPS or XPCS) -- 6. SMNs based polymeric membrane-assisted catalysis -- 6.1 Pervaporation for esterification -- 6.2 Hydrogenation. , 6.3 CO2 sequestration: hydration of CO2 -- 7. Summary and future perspectives -- Abbreviations -- References -- 8 - Semiconductor catalysts based on surface-modified nanomaterials (SMNs) for sensors -- 1. Introduction -- 2. Zero-dimensional (0D) nanomaterials -- 2.1 Quantum dots -- 2.2 Core-shell nanoparticles, hollow spheres, and nanocluster -- 3. One-dimensional (1D) nanomaterials -- 3.1 Synthesis of 1D nanostructures and sensor fabrication -- 3.2 1D NMs-based sensors -- 4. Two-dimensional (2D) nanomaterials -- 5. Tree-dimensional (3D) nanomaterials -- 6. Conclusion -- Acknowledgments -- List of resources -- References -- 9 - Surface-modified carbonaceous nanomaterials for CO2 hydrogenation and fixation -- 1. Introduction -- 1.1 Surface modified carbonaceous nanomaterials -- 2. Basic concepts of CO2 sequestration (hydrogenation and fixation) -- 3. Heterogeneous catalyst in CO2 hydrogenation -- 3.1 CO2 hydrogenation to hydrocarbons -- 3.2 CO2 hydrogenation to alcohols -- 3.3 CO2 hydrogenation to value-added products -- 4. Heterogeneous catalyst in CO2 fixation -- 4.1 CO2 fixation to cyclic carbonates -- 4.2 CO2 fixation to cyclic carbamates -- 4.3 CO2 fixation to other value-added products -- 5. Summary and perspectives -- References -- 10 - Surface-modified nanomaterials for synthesis of pharmaceuticals -- 1. Introduction -- 2. Noble metal-based nanoparticles for the synthesis of pharmaceuticals -- 3. Nonnoble metal-based nanoparticles for the synthesis of pharmaceuticals -- 4. Conclusions -- References -- 11 - Surface-modified nanomaterial-based catalytic materials for modern industry applications -- 1. Introduction -- 2. Scope of the book chapter -- 3. Active role of surface-modified nanomaterials in industry -- 3.1 Silica-modified nanomaterials -- 3.2 Graphene modified nanomaterials -- 3.3 Magnetic surface-modified nanomaterials. , 3.4 TiO2 surface-modified nanomaterials -- 4. Conclusion -- References -- 12 - Assessment of health, safety, and economics of surface-modified nanomaterials for catalytic applications: a review -- 1. Introduction -- 1.1 NMs categories and nomenclature -- 1.2 Synthesis of SNMs with the application as catalyst -- 1.3 Different types of SNMs -- 1.3.1 Carbonaceous SNMs -- 1.4 Carbon nanotubes -- 1.5 Fullerene (nC60) -- 1.6 Graphene-based nanomaterials -- 1.6.1 Metal and metal oxides -- 1.7 Other nanomaterials -- 1.7.1 Quantum dots -- 2. Human health and safety consequences of SMNs -- 3. Economic aspects of NMs used as catalysts -- 3.1 Nano zerovalent iron (nZVI) -- 3.2 CFM@PDA/Pd composite nanocatalyst -- 3.3 FeOx/C nanocatalyst -- 3.4 UV/Ni-TiO2 nanocatalyst -- 3.5 FePt-Ag nanocatalysts -- 3.6 Other nanocatalysts -- 4. Conclusions and future perspectives -- Acknowledgments -- References -- 13 - Future of SMNs catalysts for industry applications -- 1. Introduction -- 2. Nanoparticles catalysts -- 3. Catalytic applications of nanomaterial -- 3.1 Surface modification of nanoparticles and techniques -- 4. Shape and size dependent catalysts and reactions -- 4.1 Shape dependency of activity in water-gas shift -- 4.2 Oxidation -- 4.3 Hydrogenations -- 5. Metal-isolated single atoms -- 5.1 Atomic layer deposition method (ALD) -- 5.2 Isolated cluster site catalysts (ICSC) -- 5.3 Plasma -- 6. Conclusion and outlook -- References -- Index -- A -- B -- C -- D -- E -- F -- G -- H -- I -- K -- L -- M -- N -- O -- P -- Q -- R -- S -- T -- U -- V -- W -- X -- Z -- Back Cover.

Additional Edition: Print version: Gawande, Manoj B. Surface Modified Nanomaterials for Applications in Catalysis San Diego : Elsevier,c2022 ISBN 9780128233863

Language: English