UID:
edocfu_9959327474302883
Umfang:
1 online resource
ISBN:
9781444305401
,
1444305409
Inhalt:
A detailed understanding of the chemistry of surfaces and interfaces is required by many research personnel in the chemical and life science industries, as surfaces and interfaces play a critical role in many of the processes they seek to influence. Surface Chemistry of Solid and Liquid Interfaces provides a concise and easily accessible introduction to this fascinating subject. With a smooth evolution of ideas from familiar physical chemistry principles, the student can develop a sophisticated understanding of the chemistry of surfaces and interfaces. The book is also highly relevant t.
Anmerkung:
Preface; PART I: Principles; Chapter 1 Introduction to Surfaces and Interfaces; 1.1 Definition of a Surface and an Interface; 1.2 Liquids and Liquid Surfaces; 1.3 Surface Area to Volume Ratio; 1.4 Solids and Solid Surface Roughness; 1.5 Chemical Heterogeneity of Solid Surfaces; Chapter 2 Molecular Interactions; 2.1 Intramolecular Forces: Formation of a Molecule by Chemical Bonding; 2.1.1 Interatomic forces, bonds; 2.1.2 Molecular geometry; 2.1.3 Dipole moments; 2.2 Intermolecular Forces and Potential Energies; 2.3 Coulomb Interactions; 2.4 Polar Interactions.
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2.4.1 Interactions between ions and dipolar molecules (fixed and rotating)2.4.2 Interactions between dipolar molecules (fixed); 2.4.3 Keesom orientation interactions: interactions between dipolar molecules (rotating); 2.5 Induction Effects: Interactions Between Induced Non-polar and Polar Molecules; 2.5.1 Polarizability of non-polar molecules; 2.5.2 Polarizability of polar molecules; 2.5.3 Solvent medium effects and excess polarizabilities; 2.5.4 Interactions between ions and induced non-polar molecules; 2.5.5 Interactions between ions and induced polar molecules.
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2.5.6 Interactions between dipolar molecules and induced non-polar molecules (fixed)2.5.7 Debye interactions: interactions between dipolar molecules and induced dipolar molecules (rotating); 2.5.8 Unification of angle-averaged induction interactions; 2.6 van der Waals Interactions; 2.6.1 London dispersion interactions; 2.6.2 Correlation with van der Waals constants; 2.6.3 Comparison of Keesom, Debye and London interactions in polar molecules; 2.6.4 van der Waals interactions in a medium; 2.7 Repulsive Interactions, Total Interaction Pair Potentials; 2.7.1 van der Waals radius.
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2.7.2 Repulsive pair potentials2.7.3 Total intermolecular pair potentials, Mie and Lennard-Jones potentials; 2.7.4 Application of total intermolecular pair potentials in a liquid medium; 2.8 Hydrogen-bonding Interactions; 2.8.1 Properties of hydrogen bonds; 2.8.2 Hydrogen bonds in water; 2.9 Hydrophobic and Hydrophilic Interactions; 2.9.1 Hydrophobic effect; 2.9.2 Hydrophobic interactions; 2.9.3 Hydrophilic interactions; Chapter 3 Thermodynamics of Interfaces; 3.1 Introduction of Thermodynamical Concepts; 3.1.1 Thermodynamical expressions for closed systems.
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3.1.2 Thermodynamical expressions for open systems3.1.3 Equilibrium between phases in heterogeneous closed systems; 3.2 Gibbs Dividing Interface; 3.2.1 Thermodynamical definition of an interface; 3.2.2 Physical description of a real liquid interface; 3.2.3 Definitions of surface and interfacial free energy, and surface and interfacial tension; 3.2.4 Surface free energy and surface tension of liquids; 3.2.5 Thermodynamics of Gibbs dividing interface and surface excess functions; 3.3 Thermodynamics of Adsorption; 3.3.1 Gibbs adsorption isotherm; 3.3.2 Surface equation of state.
Weitere Ausg.:
Print version: Erbil, Husnu Yildirim. Surface Chemistry of Solid and Liquid Interfaces. Hoboken : John Wiley & Sons, ©2009 ISBN 9781405119689
Sprache:
Englisch
Schlagwort(e):
Electronic books.
DOI:
10.1002/9781444305401
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9781444305401
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