UID:
almahu_9948198485302882
Format:
1 online resource
ISBN:
9781119178583
,
1119178584
,
9781119178576
,
1119178576
,
1848218672
,
9781848218673
,
9781848218680
,
1848218680
,
9781119178569
,
1119178568
Series Statement:
Chemical thermodynamics set ; volume 5
Content:
The book offers advanced students, in 7 volumes, successively characterization tools phases, the study of all types of phase, liquid, gas and solid, pure or multi-component, process engineering, chemical and electrochemical equilibria, the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention was given to the rigor of mathematical developments. Besides some very specialized books, the vast majority of existing works are intended for beginners and therefore limited in scope. There is no obvious connection between the two categories of books, general books does not go far enough in generalizing concepts to enable easy reading of advanced literature. The proposed project aims to give readers the ability to read highly specialized publications based on a more general presentation of the different fields of chemical thermodynamics. Consistency is ensured between the basic concepts and applications. So we find, in the same work, the tools, their use and comparison, for a more general macroscopic description and a microscopic description of a phase.
Note:
Table of Contents -- Title -- Copyright -- Preface -- Notations and Symbols -- 1: Physico-Chemical Transformations and Equilibria -- 1.1. Characteristic parameters of physico-chemical transformations -- 1.2. Entropy production during the course of a transformation in a closed system -- 1.3. Affinity of a transformation -- 1.4. De Donder's inequality -- direction of the transformations and equilibrium conditions -- 1.5. Heats of transformation -- 1.6. Set of points representing the equilibrium states of a transformation -- 1.7. Closed systems accommodating multiple reactions -- 1.8. Direction of evolution and equilibrium conditions in an open system -- 1.9. Azeotropic transformations -- 2: Properties of States of Physico-Chemical Equilibrium -- 2.1. Laws of displacement of an equilibrium -- 2.2. Properties of all the equilibria in a system -- 2.3. Phase laws -- 2.4. Indifferent states -- 2.5. Thermodynamically-equivalent systems -- 2.6. Stability of equilibria -- 3: Molecular Chemical Equilibria -- 3.1. Law of mass action -- equilibrium constants -- 3.2. Graphical representations of equilibria -- pole diagrams -- 3.3. Representation of the evolution of an equilibrium with the temperature -- 3.4. Binary diagrams for chemical equilibrium -- 3.5. Ternary diagrams of chemical equilibria -- 3.6. Quaternary diagrams of chemical equilibria -- 4: Determination of the Values Associated with Reactions -- Equilibrium Calculations -- 4.1. Reminders of a few thermodynamic relations -- 4.2. Enthalpies of reaction -- thermochemistry -- 4.3. Reaction entropies -- 4.4. Specific heat capacities -- 4.5. Experimental determination of the equilibrium constants -- 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data -- 4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics.
,
4.8. Thermodynamic tables and databanks -- 4.9. Estimation of thermodynamic data -- 4.10. Thermodynamic calculations for complex systems -- APPENDICES -- Appendix 1: Recap on the Reference States of Solutions -- A1.1. Concentration and molar fraction -- A1.2. Chemical potentials and activity coefficients -- A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy -- Appendix 2: Recap of statistical thermodynamics -- A2.1. The three branches of statistics -- A2.2. Partition functions of a molecule object -- A2.3. Canonical partition function -- A2.4. Canonical partition functions and thermodynamic functions -- A2.5. Equilibrium constants and molecular partition functions -- Bibliography -- Index -- End User License Agreement.
Additional Edition:
Print version: Soustelle, Michel. Phase transformations. Hoboken, New Jersey : ISTE Ltd/John Wiley and Sons Inc, 2015 ISBN 9781119178576
Language:
English
Keywords:
Electronic books.
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Electronic books.
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Electronic books.
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Electronic books.
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9781119178576
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9781119178576
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9781119178576
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