UID:
almahu_9948026567602882
Umfang:
1 online resource (399 p.)
Ausgabe:
2nd updated and enl. ed.
ISBN:
1-281-00349-2
,
9786611003494
,
0-08-047492-6
Serie:
Best synthetic methods
Inhalt:
The increasing number of publications that use tellurium clearly demonstrates the important role of tellurium compounds as unique and powerful tools in a broad range of organic chemical manipulations, often characterized by their selective behavior.Tellurium in Organic Synthesis provides an overview of the principal aspects of organic tellurium chemistry. Many chapters have been enriched and updated in this second edition. New chapters include overviews of toxicology and pharmacology and a review on the preparation and reactivity of several tellurium heterocycles. The first par
Anmerkung:
Previous ed.: 1994.
,
Cover; Tellurium in Organic Synthesis: Second, Updated and Enlarged Edition; Copyright page; Contents; Foreword; Preface (1994 edition); Preface; Detailed Contents; Abbreviations; Chapter 1. Introduction; 1.1. Some Physical Properties of Tellurium; 1.2. Relevant Monographs and Review Articles; Chapter 2. Preparation of the More Important Inorganic Tellurium Reagents; 2.1. Tellurium Tetrachloride; 2.2. Tellurium Dioxide; 2.3. Alkali Metal Tellurides (Te2-Cat2+); 2.4. Alkali Metal Ditellurides (Na2Te2); 2.5. Hydrogen Telluride (H2Te); 2.6. Sodium Hydrogen Telluride (NaHTe)
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Chapter 3. Preparation of the Principal Classes of Organic Tellurium Compounds3.1. Diorganyl Tellurides; 3.2. Diorganyl Ditellurides; 3.3. Organyl Tellurols; 3.4. Bis-Organyl Telluromethanes; 3.5. Organyltellurium Trihalides; 3.6. The Products of the Hydrolysis of Aryltellurium Trihalides; 3.7. Aryltellurenyl Halides; 3.8. Aryl Tellurenyl Pseudohalides: Aryl Tellurocyanates; 3.9. Diorganyl Tellurium Dihalides; 3.10. Diorganyl Telluroxides; 3.11. Telluroesters; 3.12. Aryl Telluroformates; 3.13. Telluroglucopyranosides; 3.14. Water-Soluble Diorganyl Tellurides
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3.15. Dihaloaryltelluro Cyclopropanes3.16. Vinylic Tellurides and Ditellurides; 3.17. Acetylenic Tellurides; 3.18. Allenic and Propargylic Tellurides; Chapter 4. Tellurium in Organic Synthesis; 4.1. Reductions; 4.2. Tellurium-Mediated Formation of Anionic Species and their Reactions with Electrophiles; 4.3. Deprotection of Organic Functionality by Tellurium Reagents; 4.4. Oxidation of Organic Substances by Means of Tellurium Reagents; 4.5. Organotellurium-Based Ring Closure Reactions; 4.6. Conversion of Organotellurium Compounds into Tellurium-Free Organic Compounds; 4.7. Synthesis of Olefins
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4.8. Transmetallation Reactions4.9. Reactivity and Synthetic Applications of Vinylic Tellurides; 4.10. Free Radical Chemistry; Chapter 5. Telluroheterocycles; 5.1. Tellura-3,5-Cyclohexanedione Dichlorides (3,5-Dioxotellurane-1,1-Dichlorides); 5.2. Oxa and 1-Thia-4-Telluranes; 5.3. Tellurophenes; 5.4. 1-Benzotellurophenes; 5.5. Benzotellurepines, Tellurochromenes and Tellurochromones; 5.6. Benzo-[c]-Tellurophenes; 5.7. Telluro[3,4-c]Thiophene; 5.8. Dibenzotellurophenes; 5.9. Naphtothia-, Naphtoselena- and Naphtoditellurole; 5.10. 2H-1,3-Ditelluroles; 5.11. Tetratellurafulvalenes
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5.12. Tellurin and Derivatives of 4-H-Tellurins and 4-oxo-4- H-Tellurins (Telluropyran-4-Ones)5.13. 2H-1-Benzotellurin; 5.14. 4H-1-Benzotellurins and 4-oxo-4 H-1-Benzotellurins; 5.15. Telluroxanthenes/Telluroxanthones (and Derivatives); 5.16. Phenoxatellurins; 5.17. Phenothiatellurins/Phenoselenotellurins; 5.18. Telluranthrenes; 5.19. Bis-Thieno-1,4-Ditellurins; 5.20. 1,4-Tellurino-1,4-Tellurins; 5.21. Benzene-Fused Heterocycles Containing Tellurium, Selenium and Sulphur; 5.22. 1,5-Ditelluracyclooctane and 5H,7 H-Dibenzo[ B,G][1,5] Tellurothiocin; 5.23. Ditellurane Derivatives
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5.24. Reductive Dimerization of Telluro- And Selenoxanthone
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English
Weitere Ausg.:
ISBN 0-08-045310-4
Sprache:
Englisch
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