In:
Advanced Functional Materials, Wiley, Vol. 31, No. 24 ( 2021-06)
Kurzfassung:
Designing a semiconductor‐based heterostructure photocatalyst for achieving the efficient separation of photogenerated electron‐hole pairs is highly important for enhancing H 2 releasing photocatalysis. Here, a new class of Ni 1− x Co x Se 2 –C/ZnIn 2 S 4 hierarchical nanocages with abundant and compact ZnIn 2 S 4 nanosheets/Ni 1− x Co x Se 2 C nanosheets 2D/2D hetero–interfaces, is designed and synthesized. The constructed heterostructure photocatalyst exposes rich hetero‐junctions, supplying the broad and short transfer paths for charge carriers. The close contacts of these two kinds of nanosheets induce a strong interaction between ZnIn 2 S 4 and Ni 1− x Co x Se 2 C, improving the separation and transfer of photo‐generated electron‐hole pairs. As a consequence, the distinctive Ni 1− x Co x Se 2 C/ZnIn 2 S 4 hierarchical nanocages without using additional noble‐metal cocatalysts, display remarkable H 2 ‐relaesing photocatalytic activity with a rate of 5.10 mmol g −1 h −1 under visible light irradiation, which is 6.2 and 30 times higher than those of fresh ZnIn 2 S 4 nanosheets and bare Ni 1− x Co x Se 2 C nanocages, respectively. Spectroscopic characterizations and theory calculations reveal that the strong interaction between ZnIn 2 S 4 and Ni 1− x Co x Se 2 C 2D/2D hetero‐interfaces can powerfully promote the separation of photo‐generated charge carriers and the electrons transfer from ZnIn 2 S 4 to Ni 1− x Co x Se 2 C.
Materialart:
Online-Ressource
ISSN:
1616-301X
,
1616-3028
DOI:
10.1002/adfm.202100923
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2021
ZDB Id:
2029061-5
ZDB Id:
2039420-2
SSG:
11
