In:
Advanced Optical Materials, Wiley
Abstract:
Wide band gaps and large second harmonic generation (SHG) response are two crucial yet contradictory parameters for nonlinear optical (NLO) crystals. Herein, through exploring the influence of anion groups on structural crystallization dimension and space group, a series of new NLO Hg‐based chalcogenides A II HgM IV S 4 (A II = Sr, Ba, M IV = Si, Ge) with wide band gaps and large SHG responses have been successfully designed and synthesized. The structures of these compounds consist of 2D [HgMS 4 ] 2− (M = Si and Ge) layers composed of distorted (HgS 4 and MS 4 ) tetrahedra arranged alternately, and the layers are separated by eight‐coordinated A 2+ (A = Sr and Ba) cations. Their band gaps and SHG responses meet the basic requirements (SHG 〉 1 × AgGaS 2 ; Eg 〉 2.33 eV). Especially, SrHgSiS 4 and SrHgGeS 4 exhibit both large SHG effects (2 and 2.4 × AgGaS 2 ) and wide band gaps (3.06 and 2.97 eV), respectively, indicating they are promising IR NLO crystals. This work opens a new avenue for new NLO material design to achieve the balance between strong SHG response and large band gaps.
Type of Medium:
Online Resource
ISSN:
2195-1071
,
2195-1071
DOI:
10.1002/adom.202301735
Language:
English
Publisher:
Wiley
Publication Date:
2023
detail.hit.zdb_id:
2708158-8