In:
Advanced Synthesis & Catalysis, Wiley, Vol. 355, No. 11-12 ( 2013-08-12), p. 2179-2184
Kurzfassung:
The efficient construction of CN double bonds has been achieved by the Ir‐catalyzed intramolecular acceptorless dehydrogenative cross‐coupling of tertiary amines and amides. An iridium/2‐hydroxypyridine complex was identified as the highly efficient catalyst. A number of quinazolinone derivatives was prepared in excellent yields. An iridium‐mediated CH activation mechanism is proposed. This finding provides an unprecedented strategy for the direct imidation of sp 3 CH bonds. magnified image
Materialart:
Online-Ressource
ISSN:
1615-4150
,
1615-4169
DOI:
10.1002/adsc.v355.11/12
DOI:
10.1002/adsc.201300455
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2013
ZDB Id:
2041384-1
ZDB Id:
2033084-4
