In:
Advanced Synthesis & Catalysis, Wiley, Vol. 360, No. 6 ( 2018-03-20), p. 1151-1158
Abstract:
Ru(NNS)(PPh 3 )Cl 2 (NNS=2‐(methylthio)‐N‐(pyridin‐2‐yl‐methyl)ethan‐1‐amine) was employed in the hydrogenation of α,β‐unsaturated esters, reaching selectivities for the allylic alcohol up to 95% in the hydrogenation of iso‐butylcinnamate. In addition, several ester substrates were hydrogenated with catalyst loadings as low as 0.05 mol%. Surprisingly, selectivity of the hydrogenation of the C=O vs the C=C bonds strongly depends on the solvent. magnified image
Type of Medium:
Online Resource
ISSN:
1615-4150
,
1615-4169
DOI:
10.1002/adsc.201701607
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
2041384-1
detail.hit.zdb_id:
2033084-4