In:
Advanced Synthesis & Catalysis, Wiley, Vol. 361, No. 21 ( 2019-11-05), p. 4989-4997
Abstract:
The cheap and easily available o ‐aminophenols (OAPs) have been identified as practical directing component for the Pd‐catalyzed aromatic γ‐C−H bond arylation of phenylacetamides. Notably, the selective single and double arylation of the C−H bond(s) in the γ‐potion has been independently realized by simply modifying reaction conditions. The catalytic system of Pd(CF 3 OO) 2 /K 2 S 2 O 8 /K 2 CO 3 enables the selective single C−H arylation. On the other hand, the catalysis of Pd(OAc) 2 in the presence of KIO 3 /K 2 CO 3 induces the selective arylation of both γ‐C−H bonds. magnified image
Type of Medium:
Online Resource
ISSN:
1615-4150
,
1615-4169
DOI:
10.1002/adsc.v361.21
DOI:
10.1002/adsc.201900866
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
2041384-1
detail.hit.zdb_id:
2033084-4