In:
Angewandte Chemie, Wiley, Vol. 127, No. 8 ( 2015-02-16), p. 2450-2454
Abstract:
The simple synthetic development of acyclic pincer bis(pyridine)carbodicarbene is depicted herein. Presented is the first isolated structural pincer carbodicarbene with a C‐C‐C angle of 143°, larger than the monodentate framework. More importantly, theoretical analysis showed that this carbodicarbene embodies a more allene‐like character. Palladium complexes supported by this pincer ligand are active catalysts for Heck–Mizoroki and Suzuki–Miyaura coupling reactions.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201406481
Language:
English
Publisher:
Wiley
Publication Date:
2015
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