In:
Angewandte Chemie, Wiley, Vol. 127, No. 8 ( 2015-02-16), p. 2386-2390
Abstract:
Catalytic asymmetric aminative dearomatization of 1‐substituted 2‐naphthols was successfully implemented with electrophilic azodicarboxylates under the catalysis of chiral Sc III /pybox complexes. This intermolecular reaction represents a hitherto unknown enantioselective CN bond‐forming process through direct dearomatization of phenolic compounds to generate chiral nitrogen‐containing quaternary carbon stereocenters.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201409565
Language:
English
Publisher:
Wiley
Publication Date:
2015
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