In:
Angewandte Chemie, Wiley, Vol. 131, No. 5 ( 2019-01-28), p. 1385-1389
Abstract:
Formation of radical–radical cocrystals is an important step towards the design of organic ferrimagnets. We describe a simple approach to generate radical–radical cocrystals through the identification and implementation of well‐defined supramolecular synthons which favor cocrystallization over phase separation. In the current paper we implement the structure‐directing interactions of the E−E bond (E=S, Se) of dithiadiazolyl (DTDA) and diselenadiazolyl (DSDA) radicals to form close contacts to electronegative groups. This is exemplified through the preparation and structural characterization of three sets of radical cocrystals; the 2:2 cocrystal [PhCNSSN] 2 [MBDTA] 2 ( 4 ) [MBDTA=methyl benzodithiazolyl] and the 2:1 cocrystals [C 6 F 5 CNEEN] 2 [TEMPO] (E=S, 5 ; E=Se, 6 ). In 4 the two types of radical are linked via bifurcated inter‐dimer δ+ S⋅⋅⋅N δ− interactions whereas 5 and 6 exhibit a set of five‐centre δ+ E⋅⋅⋅O δ− contacts (E=S, Se).
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201812132
Language:
English
Publisher:
Wiley
Publication Date:
2019
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