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Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality

Kilgore, Uriah J. ; Karty, Jonathan A. ; Pink, Maren ; [weitere]

Wiley ; 2009

In: Angewandte Chemie International Edition Vol. 48, No. 13 ( 2009-03-16), p. 2394-2397

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In: Angewandte Chemie International Edition, Wiley, Vol. 48, No. 13 ( 2009-03-16), p. 2394-2397

Kurzfassung: The vanadium–bis(telluride) complex , [(PNP)V(Te) 2 ] (see picture), in which the terminal telluride units can act as leaving groups or protecting groups, is prepared by activation of elemental Te by V. The complex masks {(PNP)V I } or {(PNP)V III } sources when exposed to oxidants such as azides and diphenyldiazomethane. Isocyanides promote elimination of one Te ligand to furnish a V III complex with a terminal telluride ligand. magnified image

Materialart: Online-Ressource

ISSN: 1433-7851 , 1521-3773

URL: Issue

URL: Article

DOI: 10.1002/anie.v48:13

DOI: 10.1002/anie.200806022

RVK:

VA 2100

Sprache: Englisch

Verlag: Wiley

Publikationsdatum: 2009

ZDB Id: 2011836-3