In:
Angewandte Chemie International Edition, Wiley, Vol. 48, No. 26 ( 2009-06-15), p. 4652-4652
Abstract:
Bidirectional chemo‐switching of magnetism occurs in a microporous coordination polymer containing spin‐crossover subunits, as described by M. Ohba, J. A. Real, S. Kitagawa, and co‐workers in their Communication on page 4767 ff. In situ magnetic measurements reveal that most guest molecules transform the framework spin state from diamagnetic low spin (red) to paramagnetic high spin (yellow), whereas the guest CS 2 stabilizes the low‐spin state. These induced spin states are retained as a memory effect after the release of the guest. magnified image
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.200990134
Language:
English
Publisher:
Wiley
Publication Date:
2009
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7