In:
Angewandte Chemie International Edition, Wiley, Vol. 55, No. 43 ( 2016-10-17), p. 13446-13449
Kurzfassung:
A new intermetallic compound, the first to be structurally identified in the Cu−Bi binary system, is reported. This compound is accessed by high‐pressure reaction of the elements. Its detailed characterization, physical property measurements, and ab initio calculations are described. The commensurate crystal structure of Cu 11 Bi 7 is a unique variation of the NiAs structure type. Temperature‐dependent electrical resistivity and heat capacity measurements reveal a bulk superconducting transition at T c =1.36 K. Density functional theory calculations further demonstrate that Cu 11 Bi 7 can be stabilized (relative to decomposition into the elements) at high pressure and temperature. These results highlight the ability of high‐pressure syntheses to allow for inroads into heretofore‐undiscovered intermetallic systems for which no thermodynamically stable binaries are known.
Materialart:
Online-Ressource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.201605902
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2016
ZDB Id:
2011836-3
ZDB Id:
123227-7