In:
Angewandte Chemie International Edition, Wiley, Vol. 57, No. 27 ( 2018-07-02), p. 7992-7996
Abstract:
Nitrogen‐enriched porous nanocarbon, graphene, and conductive polymers attract increasing attention for application in supercapacitors. However, electrode materials with a large specific surface area (SSA) and a high nitrogen doping concentration, which is needed for excellent supercapacitors, has not been achieved thus far. Herein, we developed a class of tetracyanoquinodimethane‐derived conductive microporous covalent triazine‐based frameworks (TCNQ‐CTFs) with both high nitrogen content ( 〉 8 %) and large SSA ( 〉 3600 m 2 g −1 ). These CTFs exhibited excellent specific capacitances with the highest value exceeding 380 F g −1 , considerable energy density of 42.8 Wh kg −1 , and remarkable cycling stability without any capacitance degradation after 10 000 cycles. This class of CTFs should hold a great potential as high‐performance electrode material for electrochemical energy‐storage systems.
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.201711169
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7