In:
Angewandte Chemie International Edition, Wiley, Vol. 62, No. 27 ( 2023-07-03)
Abstract:
Cobalt ferrite (CoFe 2 O 4 ) spinel has been found to produce C 2 −C 4 hydrocarbons in a single‐step, ambient‐pressure, photocatalytic hydrogenation of CO 2 with a rate of 1.1 mmol g −1 h −1 , selectivity of 29.8 % and conversion yield of 12.9 %. On stream the CoFe 2 O 4 reconstructs to a CoFe−CoFe 2 O 4 alloy‐spinel nanocomposite which facilitates the light‐assisted transformation of CO 2 to CO and hydrogenation of the CO to C 2 −C 4 hydrocarbons. Promising results obtained from a laboratory demonstrator bode well for the development of a solar hydrocarbon pilot refinery.
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.202304470
Language:
English
Publisher:
Wiley
Publication Date:
2023
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7