In:
Applied Organometallic Chemistry, Wiley, Vol. 26, No. 7 ( 2012-07), p. 323-329
Abstract:
New N ‐silver(I) acetylbenzamide complexes of type L n ⋅AgNC 9 H 8 O 2 (L = PPh 3 ; n = 1, 2a; n = 2, 2b; n = 3, 2c; L = P(OEt) 3 ; n = 1, 2d; n = 2, 2e; n = 3, 2f) were prepared. These complexes were obtained in high yields and characterized by elemental analysis, 1 H NMR, 13 C{H} NMR, 31 P{H} NMR and IR spectroscopy, respectively. The molecular structure of 2b has been determined by X‐ray single‐crystal analysis in which the silver atom is in a distorted tetrahedral geometry and crystallizes as cis–trans . New N ‐silver(I) acetylbenzamide complexes have a four‐membered ring, which could influence their chemical and physical properties and modulate volatility. Metal organic chemical vapor deposition experiments were carried out successfully at 400°C and 450°C using 2e as precursor for the deposition of silver films, respectively. The high‐purity silver film obtained at 400°C is dense and homogeneous. Copyright © 2012 John Wiley & Sons, Ltd.
Type of Medium:
Online Resource
ISSN:
0268-2605
,
1099-0739
Language:
English
Publisher:
Wiley
Publication Date:
2012
detail.hit.zdb_id:
1480791-9
