In:
Chemistry – An Asian Journal, Wiley, Vol. 12, No. 18 ( 2017-09-19), p. 2441-2446
Abstract:
A flexible one‐pot strategy with pyramidal Se IV heteroatoms was employed for the assembly of the praseodymium‐containing gly‐decorated polyoxotungstate [{Pr 3 (H 2 O) 10 [Se 2 W 22 O 76 (gly) 2 ]} 2 (Se 2 W 7 O 30 H 2 )] 18− ( 1 a ), which is constructed from one {Se 2 W 7 O 30 H 2 } unit and two identical {Pr 3 (H 2 O) 10 [Se 2 W 22 O 76 (gly) 2 ]} units. Furthermore, the catalytic performance of Cs 2 Na 4 H 12 [{Pr 3 (H 2 O) 10 [Se 2 W 22 O 76 (gly) 2 ]} 2 (Se 2 W 7 O 30 H 2 )] ⋅ 25 H 2 O ( 1 ) for alkene epoxidation with hydrogen peroxide was investigated under mild reaction conditions, and the experimental results suggested that compound 1 exhibits good catalytic performance for the epoxidation of cyclooctene.
Type of Medium:
Online Resource
ISSN:
1861-4728
,
1861-471X
DOI:
10.1002/asia.201700801
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
2233006-9