In:
Chemistry – An Asian Journal, Wiley, Vol. 17, No. 15 ( 2022-08)
Abstract:
An efficient silver‐promoted decarboxylative gem ‐difluoromethylenation of aryl‐ or alkyl‐substituted α,β‐unsaturated carboxylic acids with readily available benzo‐1,3‐diazolic difluoromethyl bromides has been developed. This convenient transformation demonstrated good functional‐group tolerability and broad substrate scope, and afforded the allylic difluorides in good to excellent yields with exclusive E ‐stereoselectivity under mild reaction conditions.
Type of Medium:
Online Resource
ISSN:
1861-4728
,
1861-471X
DOI:
10.1002/asia.202200448
Language:
English
Publisher:
Wiley
Publication Date:
2022
detail.hit.zdb_id:
2233006-9