In:
Chemistry – A European Journal, Wiley, Vol. 24, No. 1 ( 2018-01-02), p. 56-61
Kurzfassung:
On‐surface reactions based on metal‐catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on‐surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra‐high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an on‐surface Ullmann‐type coupling reaction by inhibiting one potential intermediate structure and stabilising another.
Materialart:
Online-Ressource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201704693
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2018
ZDB Id:
1478547-X
