In:
Chemistry – A European Journal, Wiley, Vol. 24, No. 41 ( 2018-07-20), p. 10409-10421
Kurzfassung:
Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized by vibrational spectroscopy in the gaseous and liquid phase as well as in the Ar‐matrix. By varying the temperature, certain bands could be assigned to several conformers. Gas‐phase electron diffraction revealed a dominance of the anti ‐conformer at ambient temperature. The same conformation was found in the solid state. Via the in situ technique for crystallization, not less than four different modifications were identified. Among these different modifications, the structural parameters of the molecules remain relatively constant, but the aggregation pattern changes. Although the molecules aggregate by chlorine⋅⋅⋅oxygen contacts in each modification, the geometrical parameters of these interaction show significant differences and were evaluated and are in part inconsistent with the halogen bonding concept.
Materialart:
Online-Ressource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201800817
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2018
ZDB Id:
1478547-X
