In:
Chemistry – A European Journal, Wiley, Vol. 24, No. 49 ( 2018-09-03), p. 12983-12991
Kurzfassung:
Donor–acceptor (D–A) complexes between 3,4‐dicyano‐1,2,5‐chalcogenadiazoles [chalcogen=Te ( 1 a ), Se ( 1 b ), S ( 1 c )] and the pseudohalides CN − and XCN − (X=O, S, Se, Te) were studied experimentally and theoretically. For 1 a , they were isolated as [K(18‐crown‐6)][ 1 a ‐CN] ( 2 ), [K(18‐crown‐6)][ 1 a ‐NCO] ( 3 ), [K(18‐crown‐6)][ 1 a ‐SCN] ( 4 ), [K(18‐crown‐6)][ 1 a ‐SeCN] ( 5 ), and [K][ 1 a ‐NCSe] ( 6 ) and characterized by X‐ray diffraction (XRD), UV/Vis and NMR spectroscopy, and DFT and QTAIM calculations. For 1 b and 1 c , the complexes were not isolated due to unfavorable thermodynamics. In all isolated complexes, the D–A bonds, stabilized by negative hyperconjugation, were longer than the sum of the covalent radii and shorter than the sum of the van der Waals radii of the bonded atoms. In mixtures of 1 a , F − , and SeCN − , the complex [ 1 a ‐F] − was selectively formed in accordance with thermodynamics. The reaction of 1 a with SeCN − and the cyclic trimeric perfluoro‐ ortho ‐phenylene mercury afforded the complex [K(18‐crown‐6)][SCN] ⋅ ( o ‐C 6 F 4 Hg) 3 , which was characterized by XRD.
Materialart:
Online-Ressource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201802257
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2018
ZDB Id:
1478547-X
