In:
Chemistry – A European Journal, Wiley, Vol. 26, No. 4 ( 2020-01-16), p. 853-862
Abstract:
The Fe‐based transition metal oxides are promising anode candidates for lithium storage considering their high specific capacity, low cost, and environmental compatibility. However, the poor electron/ion conductivity and significant volume stress limit their cycle and rate performances. Furthermore, the phenomena of capacity rise and sudden decay for α‐Fe 2 O 3 have appeared in most reports. Here, a uniform micro/nano α‐Fe 2 O 3 nanoaggregate conformably enclosed in an ultrathin N‐doped carbon network (denoted as M/N‐α‐Fe 2 O 3 @NC) is designed. The M/N porous balls combine the merits of secondary nanoparticles to shorten the Li + transportation pathways as well as alleviating volume expansion, and primary microballs to stabilize the electrode/electrolyte interface. Furthermore, the ultrathin carbon shell favors fast electron transfer and protects the electrode from electrolyte corrosion. Therefore, the M/N‐α‐Fe 2 O 3 @NC electrode delivers an excellent reversible capacity of 901 mA h g −1 with capacity retention up to 94.0 % after 200 cycles at 0.2 A g −1 . Notably, the capacity rise does not happen during cycling. Moreover, the lithium storage mechanism is elucidated by ex situ XRD and HRTEM experiments. It is verified that the reversible phase transformation of α↔γ occurs during the first cycle, whereas only the α‐Fe 2 O 3 phase is reversibly transformed during subsequent cycles. This study offers a simple and scalable strategy for the practical application of high‐performance Fe 2 O 3 electrodes.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201903893
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
1478547-X
