In:
Chinese Journal of Chemistry, Wiley, Vol. 22, No. 7 ( 2004-07), p. 757-760
Abstract:
The chiral clusters (μ 3 ‐S)MCoW(CO) 8 [ n 5 ‐C 5 H 4 C(O)OCH 3 ] =Ru (2), Fe (3)] were synthesized by asymmetric induction of N‐benzylcinchonium chloride as phase‐transfer catalyst (PTC). The most suitable amount of PTC is 70 mol%. Cluster 3 was determined by single crystal X‐ray diffraction analysis. The best ee of the chiral cluster is over 20%.
Type of Medium:
Online Resource
ISSN:
1001-604X
,
1614-7065
DOI:
10.1002/cjoc.20040220728
Language:
English
Publisher:
Wiley
Publication Date:
2004
detail.hit.zdb_id:
2144352-X
SSG:
6,25