In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2013, No. 18 ( 2013-06-12), p. 3185-3190
Abstract:
For the first time, single crystals of KPbBP 2 O 8 with sizes up to 18 × 13 × 6 mm have been grown from a stoichiometric mixture of its components by the top seed growth method. The crystal structure was determined from single‐crystal X‐ray data: tetragonal, space group I $\bar {4}$ 2 d , a = 7.1464(7) Å, c = 13.8917(16) Å, Z = 4. It exhibits an isolated [BP 2 O 8 ] 3– unit that is built from nearly ideal tetrahedral BO 4 and PO 4 groups, which are connected to each other alternatively by corner‐sharing O atoms to make a 12‐membered ring. Transmission spectroscopy illustrates that the UV cutoff edge is at approximately 235 nm. Furthermore, IR spectroscopy, thermal analysis, and second‐harmonic generation (SHG) measurements were also performed on the reported material.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2013.18
DOI:
10.1002/ejic.201300009
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
1475009-0