In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2013, No. 35 ( 2013-12-02), p. 6049-6059
Abstract:
Orange‐red trinuclear nickel(II) complexes are obtained by reacting Ni(ClO 4 ) 2 (H 2 O) 6 with 3(5)‐arylpyrazoles in the presence of a base. Herein, the diamagnetic nickel centers are coordinated in a square‐pyramidal manner by four pyrazolato ligands, each of which bridges two nickel sites. The structurally unique complexes were investigated by NMR, IR, fluorescence, and X‐ray spectroscopy. All seven compounds described here were structurally elucidated by single‐crystal X‐ray diffraction. With 3(5)‐ferrocenylpyrazole as the substrate, a nonametallic system that possesses six redox‐active ferrocenyl moieties was obtained.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2013.35
DOI:
10.1002/ejic.201300925
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
1475009-0