In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2013, No. 32 ( 2013-11-04), p. 5528-5533
Abstract:
The noncentrosymmetric borate CsCdBO 3 was synthesized by a solid‐state reaction, and its structure was determined by single‐crystal X‐ray diffraction. The crystal structure is a complicated three‐dimensional network composed of CdO 6 octahedra, CsO 6 octahedra, and BO 3 triangles. Interestingly, CsCdBO 3 crystallizes in the cubic space group P 2 1 3, which is quite rare for borate‐containing anisotropic polarized planar BO 3 groups. Furthermore, the IR spectrum confirms the presence of BO 3 groups. Second harmonic generation (SHG) measurements on powder samples reveal that the SHG response of CsCdBO 3 is approximately 0.5 × KDP (KH 2 PO 4 ). Thermal analysis and UV/Vis/NIR diffuse reflectance spectroscopy data, as well as electronic band structure calculations, are also reported.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2013.32
DOI:
10.1002/ejic.201301075
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
1475009-0