In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2014, No. 22 ( 2014-08), p. 3467-3473
Abstract:
Compounds containing both B–O and P–O groups are of wide interest and have been classified into borophosphates and borate–phosphates by R. Kniep et al. In addition to the B/P ratio, analysis results show that regulating the [M/(B+P)] ratio is also an effective strategy to synthesize new borate–phosphates. The first lithium lead borate–phosphate, LiPb 4 (BO 3 )(PO 4 ) 2 , was synthesized by regulating this ratio. This compound crystallizes in the orthorhombic space group Pbca (No. 61). It possesses a 3D structure with a corrugated 2D layer of [B 2 Pb 8 O 18 ] ∞ that is further connected by a [LiP 2 O 8 ] ∞ chain; both BO 3 and PO 4 were isolated. First‐principle theoretical studies were performed to aid the understanding of the electronic structures and the linear optical properties. In addition, thermal analysis, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy were performed on the reported material.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2014.22
DOI:
10.1002/ejic.201402389
Language:
English
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
1475009-0