In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2019, No. 3-4 ( 2019-01-31), p. 523-528
Abstract:
The nonclassical heteropolyoxotungstate [P 3 W 6 (O 2 ) 6 (OH) 2 O 22 ] 7– has been successfully synthesized and characterized well by various techniques such as FT‐IR, UV/Vis, TGA, as well as elemental analysis. The single‐crystal X‐ray analysis reveals that the two {PW 3 (O 2 ) 3 (OH)O 9 } subunits are linked together through a {PO 4 } group, forming a nonclassical type of phosphotungstate polyanionic framework. Furthermore, the solution behaviour of the title compound has been investigated by UV/Vis spectroscopy, electrospray ionization mass spectrometry and 31 P nuclear magnetic resonance spectroscopy.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2019.3-4
DOI:
10.1002/ejic.201800556
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
1475009-0