In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2020, No. 29 ( 2020-08-09), p. 2809-2815
Abstract:
In order to gain information about the behavior of tin sulfide clusters with bio‐organic ligand shells under acidic conditions, such as found in undesirable cells for instance, we systematically treated amino acid‐functionalized tin sulfide clusters with different acids. For Boc‐protected amino acid derivatives, we could show that this treatment causes either cleavage of the protecting group of the amino acid or protolysis of the tin sulfide core under release of H 2 S and formation of the correspondingly functionalized organotin trichloride, depending on the nature of the acid. This points towards a potential future use of such species for targeted cytotoxic applications.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2020.29
DOI:
10.1002/ejic.202000290
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
1475009-0