In:
European Journal of Organic Chemistry, Wiley, Vol. 2010, No. 11 ( 2010-04), p. 2132-2137
Abstract:
The products of the gas‐phase pyrolysis of two regioisomeric 1,2,4‐trithiolane S ‐oxides were collected in an argon matrix at 10 K and studied by means of spectroscopic as well as computational methods. Whereas the main products of the pyrolysis of the “symmetrical” S ‐oxide were identified asthioformaldehyde S ‐oxide and thioformaldehyde S ‐sulfide, the “non‐symmetrical” S ‐oxide gave predominantly dithioformic acid, which exists as a mixture of s ‐ cis and s ‐ trans conformers. We present a rationalization of the reaction pathways including density functional theory computations.
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2010:11
DOI:
10.1002/ejoc.200901440
Language:
English
Publisher:
Wiley
Publication Date:
2010
detail.hit.zdb_id:
1475010-7