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Total Synthesis of (–)‐Isopisiferin: Confirmation of Absolute Configuration

Jan, Ning‐Wei ; Liu, Hsing‐Jang ; Hsieh, Min‐Tsang ; [weitere]

Wiley ; 2010

In: European Journal of Organic Chemistry Vol. 2010, No. 22 ( 2010-08), p. 4271-4275

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In: European Journal of Organic Chemistry, Wiley, Vol. 2010, No. 22 ( 2010-08), p. 4271-4275

Kurzfassung: Starting from 4,4‐dimethyl‐2‐cyclohexenone, an enantioselective synthesis of (–)‐isopisiferin has been accomplished in 15 steps with an overall yield of 11.4 %. This work not only provides synthetic evidence for confirming the absolute configuration of natural isopisiferin itself, but also serves as an additional correlation origin to which many related icetexane‐type diterpenes, particular for the pisiferin family, can be referred.

Materialart: Online-Ressource

ISSN: 1434-193X , 1099-0690

URL: Issue

URL: Article

DOI: 10.1002/ejoc.v2010:22

DOI: 10.1002/ejoc.201000449

RVK:

VA 4073

Sprache: Englisch

Verlag: Wiley

Publikationsdatum: 2010

ZDB Id: 1475010-7